Mechanism of dopant segregation to SiO2/Si(001) interfaces

被引:20
作者
Dabrowski, J [1 ]
Casali, RA [1 ]
Müssig, HJ [1 ]
Baierle, R [1 ]
Caldas, MJ [1 ]
Zavodinsky, V [1 ]
机构
[1] IHP, D-15236 Frankfurt, Germany
来源
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B | 2000年 / 18卷 / 04期
关键词
D O I
10.1116/1.1306310
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Dopant atoms segregate to SiO2/Si(001) interfaces and are deactivated there. This can cause problems in fabrication of submicron microelectronic devices. On the basis of ab initio calculations, we propose a mechanism for donor segregation and deactivation. We argue that donor species (P and As) are trapped as threefold-coordinated atoms at interface defect sites (dangling bonds and Si vacancies) and, most significantly, in form of dopant pairs at defect-free interfaces. This pairing will dominate when dopant concentration exceeds approximately 10(19) cm(-3). (C) 2000 American Vacuum Society. [S0734-211X(00)08504-8].
引用
收藏
页码:2160 / 2164
页数:5
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