Super-flexible bis(trifluoromethanesulfonyl)-amide doped graphene transparent conductive electrodes for photo-stable perovskite solar cells

被引:98
作者
Heo, Jin Hyuck [1 ]
Shin, Dong Hee [1 ]
Song, Dae Ho [1 ]
Kim, Do Hun [1 ]
Lee, Sang Jin [1 ]
Im, Sang Hyuk [1 ]
机构
[1] Korea Univ, Dept Chem & Biol Engn, 145 Anam Ro, Seoul 136713, South Korea
基金
新加坡国家研究基金会;
关键词
ULTRATHIN; LAYERS; FILM;
D O I
10.1039/c8ta02672f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Super-flexible bis(trifluoromethanesulfonyl)-amide (TFSA)-doped graphene transparent conducting electrode (GR TCE)-based FAPbI(3-x)Br(x) perovskite solar cells with 18.9% power conversion efficiency (PCE) for a rigid device and 18.3% for a flexible one are demonstrated because the TFSA-doped GR TCE reveals high conductivity and high transmittance. The unencapsulated TFSA-doped GR TCE-based cell maintained similar to 95% of its initial PCE under a continuous light soaking of 1 Sun at 60 degrees C/30% relative humidity for 1000 h. In addition, the TFSA-doped GR TCE-based flexible perovskite solar cells show excellent bending stabilities, maintaining PCEs of similar to 85, similar to 75, and similar to 35% of their original values after 5000 bending cycles, at R = 12, 8, and 4 mm, respectively.
引用
收藏
页码:8251 / 8258
页数:8
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