Observation of reaction intermediates and kinetic mistakes in a remarkably slow self-assembly reaction

被引：39
作者：
Cangelosi, Virginia M.
Carter, Timothy G.
Zakharov, Lev N.
Johnson, Darren W. [1 ]
机构：
[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 37期
基金：
美国国家科学基金会;
关键词：
TRIPLE-STRANDED HELICATE; SUPRAMOLECULAR CHEMISTRY; COORDINATION CHEMISTRY; RATIONAL DESIGN; MECHANISM; COMPLEX; METALS; ORGANIZATION; MACROCYCLES; LIGANDS;
D O I：
10.1039/b914750k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Several intermediates and oligomeric mistakes in a metal-ligand self-assembly reaction are identified by H-1 NMR, MALDI-MS, and XRD, providing evidence in support of multiple pathways in the "free-for-all" self-assembly process.
引用
收藏
页码：5606 / 5608
页数：3
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