An intramolecular aza-[3+3] annulation approach to azaphenalene alkaloids.: Total synthesis of myrrhine

被引：39

作者：

Gerasyuto, Aleksey I. ^{[1
]}

Hsung, Richard P. ^{[1
]}

机构：

[1] Univ Wisconsin, Div Pharmaceut Sci, Madison, WI 53705 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 07期

关键词：

D O I：

10.1021/jo062533h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A detailed account on the stereoselective total syntheses of azaphenalene alkaloids via an intramolecular aza-[3 + 3] annulation strategy is described here. All five members of the Coccinellidae family of defensive alkaloids were prepared from the same common intermediate, which was derived from a stereoselective aza-[3 + 3] annulation reaction.

引用

页码：2476 / 2484

页数：9

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