Isolation and Structural Characterization of the Molecular Nanocapsule Sm2@D3d(822)-C104

被引：72

作者：

Mercado, Brandon Q. ^{[2
]}

Jiang, An

Yang, Hua ^{[1
]}

Wang, Zhimin ^{[1
]}

Jin, Hongxiao ^{[1
]}

Liu, Ziyang ^{[1
]}

Olmstead, Marilyn M. ^{[2
]}

Balch, Alan L. ^{[2
]}

机构：

[1] Zhejiang Univ, Dept Chem, Zhejiang Calif Int Nanosyst Inst, Hangzhou 310027, Peoples R China

[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 48期

基金：

美国国家科学基金会;

关键词：

carbon nanotubes; endohedral fullerenes; nanocapsules; samarium; X-ray diffraction; ENDOHEDRAL FULLERENES; CRYSTALLOGRAPHIC CHARACTERIZATION; C-88; CAGE; FAMILY; METALLOFULLERENE; CLUSTER;

D O I：

10.1002/anie.200904662

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bigger the more tubular? Structural characterization of Sm 2@D3d(822)-C104 reveals that it is a member of a new class of nanocapsules with a carbon cage that resembles a small end-capped carbon nanotube. This remarkable molecule is the largest endohedral fullerene to be crystallographically characterized to date and is nearly twice the size of the prototypical C60. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9114 / 9116

页数：3

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