Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex

被引：33

作者：

Cui, Li-Ying ^{[1
]}

Yang, Jin ^{[1
]}

Fu, Qiang ^{[1
]}

Zhao, Bao-Zhong ^{[1
]}

Tian, Lei ^{[1
]}

Yu, Hai-Ling ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2007年 / 827卷 / 1-3期

关键词：

ZnPc; crystal structure; FT-IR; UV-vis; fluorescence;

D O I：

10.1016/j.molstruc.2006.05.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new complex [ZnPc(H2O)](.)2DMF (1), where Pe = phthalocyanine and DMF = NN-dimethylformamide, has been synthesized and its crystal has been determined by single-crystal X-ray diffraction method. The compound crystallizes in the triclinic space group P - 1. The lattice parameters are a = 11.668(5) angstrom, b = 12.186(5) angstrom, c = 13.939(6) angstrom, alpha = 78.697(7)degrees, beta = 88.045 (7)degrees, gamma = 62.949(7)degrees, V=1727.4(12) angstrom(3) and Z = 2. The Zn(II) ion is five-coordinated by four nitrogen atoms from Pc ligands and one oxygen atom from one water molecule. Notably, there are strong pi-pi interactions between Pc ligands, leading to 1D superamolecular structure. Moreover, the elemental analyses, FT-IR, UV-vis and Fluorescence spectra for this complex were also determined. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：149 / 154

页数：6

共 32 条

[1]

Bandin M., 1989, J ELECTROANAL CHEM, V271, P173

[2] GAP PHTHALOCYANINE LANGMUIR-BLODGETT FILM ELECTROLUMINESCENT DIODE [J].

BATEY, J ;

PETTY, MC ;

ROBERTS, GG ;

WIGHT, DR .

ELECTRONICS LETTERS, 1984, 20 (12) :489-491

[3] PHOTOSENSITIZERS OF THE PORPHYRIN AND PHTHALOCYANINE SERIES FOR PHOTODYNAMIC THERAPY [J].

BONNETT, R .

CHEMICAL SOCIETY REVIEWS, 1995, 24 (01) :19-33

[4] The products of the action of acet-anhydride on phthalamide. [J].

Braun, A ;

Tcherniac, J .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1907, 40 :2709-2714

[5] CRYSTAL STRUCTURE OF BETA-COPPER PHTHALOCYANINE [J].

BROWN, CJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (10) :2488-&

[6] METAL PHTHALOCYANINES AND PORPHYRINS AS PHOTOSENSITIZERS FOR REDUCTION OF WATER TO HYDROGEN [J].

DARWENT, JR ;

DOUGLAS, P ;

HARRIMAN, A ;

PORTER, G ;

RICHOUX, MC .

COORDINATION CHEMISTRY REVIEWS, 1982, 44 (01) :83-126

[7]

DENEUX MM, 1985, INORG CHEM, V24, P1878

[8] Vibrational spectra and structure of zinc phthalocyanine [J].

Ding, HM ;

Wang, S ;

Xi, SQ .

JOURNAL OF MOLECULAR STRUCTURE, 1999, 475 (2-3) :175-180

[9] STEREOCHEMISTRY OF COORDINATION GROUP IN AN IRON(3) DERIVATIVE OF TETRAPHENYLPORPHINE [J].

HOARD, JL ;

COHEN, GH ;

GLICK, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (09) :1992-&

[10] Synthesis, crystal structure and characterisation of aquamagnesium phthalocyanine-MgPc(H2O).: The origin of an intense near-IR absorption of magnesium phthalocyanine known as 'X-phase' [J].

Janczak, J ;

Idemori, YM .

POLYHEDRON, 2003, 22 (09) :1167-1181

← 1 2 3 4 →