The production of activated carbon from cation exchange resin for high-performance supercapacitor

被引:22
作者
Zhang, Zhong Jie [1 ,2 ]
Cui, Peng [1 ]
Chen, Xiang Ying [1 ]
Liu, Jian Wei [3 ]
机构
[1] Hefei Univ Technol, Sch Chem Engn, Anhui Key Lab Controllable Chem React & Mat Chem, Hefei 230009, Anhui, Peoples R China
[2] Anhui Univ, Coll Chem & Chem Engn, Anhui Prov Key Lab Environm Friendly Polymer Mat, Hefei 230039, Anhui, Peoples R China
[3] Univ Kansas, Dept Phys & Astron, Lawrence, KS 66045 USA
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Cation exchange resin; Activated carbon; Supercapacitor; Electrode materials; HIGH-SURFACE-AREA; ENERGY-STORAGE; KOH ACTIVATION; ELECTROCHEMICAL CAPACITORS; MESOPOROUS CARBONS; NANOPOROUS CARBON; NANOFIBERS; XPS; ADSORBENTS; CHEMISTRY;
D O I
10.1007/s10008-013-2039-x
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
High-performance activated carbon for electrochemical double-layer capacitors (EDLC) has been prepared from cation exchange resin by carbonization and subsequent activation with KOH. The activation temperature has a key role in the determination of porous carbon possessing high surface areas, and large pore structures. The porous carbon activated at 700 degrees C (carbon-700-1:4) has high surface area (2236 m(2)g(-1)) and large total pore volume (1.15 cm(3)g(-1)), which also displays best capacitive performances due to its well-balanced micro-or mesoporosity distribution. In details, specific capacitances of the carbon-700-1: 4 sample are 336.5 Fg(-1) at a current density of 1 Ag-1 and 331.8 Fg(-1) at 2 Ag-1. At high current density as 20 Ag-1, the retention of its specific capacitance is 68.4 %. The carbon-700-1: 4 sample also exhibits high performance of energy density (46.7 Whkg(-1)) and long cycle stability (similar to 8.9 % loss after 3,000 cycles). More importantly, due to the amount of waste ion-exchange resins increasing all over the world, the present synthetic method might be adopted to dispose them, producing high-performance porous carbons for EDLC electrode materials.
引用
收藏
页码:1749 / 1758
页数:10
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