Crystal structure, magnetic properties, and magnetization variation in Bi0.84La0.16Fe1-xTixO3 polycrystalline ceramic

被引:9
|
作者
Tho, P. T. [1 ]
Nghia, N. X. [2 ]
Khiem, L. H. [2 ]
Hao, N. V. [1 ]
Ha, L. T. [1 ]
Hoa, V. X. [1 ]
Xuan, C. T. A. [1 ]
Lee, B. W. [3 ,4 ]
Dang, N. V. [1 ]
机构
[1] Thai Nguyen Univ Sci, Dept Phys & Technol, Thai Nguyen, Vietnam
[2] Vietnam Acad Sci & Technol, Inst Phys, 18 Hoang Quoc Viet, Hanoi, Vietnam
[3] Hankuk Univ Foreign Studies, Dept Phys, Yongin 449791, South Korea
[4] Hankuk Univ Foreign Studies, Oxide Res Ctr, Yongin 449791, South Korea
基金
新加坡国家研究基金会;
关键词
BiFeO3-based multiferroics; Magnetic properties; Isothermal structural transition; DOPED BIFEO3 CERAMICS; EXCHANGE BIAS; ENHANCEMENT; DISTORTION; LA; GD; FERROMAGNETISM; MULTIFERROICS; HYSTERESIS; TRANSITION;
D O I
10.1016/j.ceramint.2018.10.225
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The crystal structure, microstructure, and magnetic properties of Bi0.84La0.16Fe1-xTixO3 (x = 0.1, 0.14, 0.16, 0.2) ceramic samples prepared by solid-state reaction are investigated by combining X-ray diffraction, Raman scattering, scanning electron microscope, and magnetic measurements. The analysis of crystal structure reveals the presence of multiphase structures and the gradual formation of Aurivillus Bi5FeTi3O15 phase when increasing Ti concentration. The microstructure study shows several grain shapes, corresponding to the different crystal structures and phases present in the sample. The competition in lattice strain of the coexisting phases leads to the isothermal structural transition and the self-change in magnetization. A drastic decrease in coercivity and an increase in magnetization are observed with increasing ferromagnetic-like hysteresis loops. The change in magnetic properties of the samples is strongly dependent on the coexisting phases in the samples.
引用
收藏
页码:3223 / 3229
页数:7
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