Chemically designed Pt/PPy nano-composite for effective LPG gas sensor

被引:36
作者
Gaikwad, Namrata [1 ]
Bhanoth, Sreenu [1 ]
More, Priyesh V. [1 ]
Jain, G. H. [2 ]
Khanna, P. K. [1 ]
机构
[1] Govt India, DIAT, Dept Appl Chem, Nanochem Nanomat Lab, Pune 411025, Maharashtra, India
[2] KTHM Coll, Nasik 422005, India
关键词
ELECTROCATALYTIC OXIDATION; PLATINUM MICROPARTICLES; POLYMER NANOCOMPOSITES; POLYPYRROLE NANOTUBES; CONDUCTING POLYMERS; HOLLOW SPHERES; D-GLUCOSE; METHANOL; NANOPARTICLES; ELECTRODES;
D O I
10.1039/c3nr05375j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Simultaneous in situ reduction of hexachloroplatinic acid by the amine group in the pyrrole monomer and oxidation of pyrrole to form polypyrrole (PPy) was examined. The reactions were performed at various temperatures to understand the degree of reduction of platinum precursor as well as doping of polypyrrole with Pt(II) chloro-complex. Spectroscopic images revealed different morphologies for the Pt/PPy nano-composite prepared at various temperatures. The as-prepared Pt/PPy nano-composite samples were tested for their ability to sense liquefied petroleum gas (LPG) which resulted in excellent sensing at relatively low temperature. The porous nature and ohmic contact between the PPy and platinum nanoparticles makes the as-prepared Pt/PPy nano-composite highly useful for sensors as well as electronic applications.
引用
收藏
页码:2746 / 2751
页数:6
相关论文
共 51 条
[41]   OXIDATION OF HYDROGEN AT PLATINUM POLYPYRROLE ELECTRODES [J].
VORK, FTA ;
JANSSEN, LJJ ;
BARENDRECHT, E .
ELECTROCHIMICA ACTA, 1986, 31 (12) :1569-1575
[42]   One-step synthesis of polypyrrole-Ag nanofiber composites in dilute mixed CTAB/SDS aqueous solution [J].
Xing, Shuangxi ;
Zhao, Guoku .
MATERIALS LETTERS, 2007, 61 (10) :2040-2044
[43]   Decorating Polypyrrole Nanotubes with Au Nanoparticles by an In Situ Reduction Process [J].
Xu, Jingjing ;
Hu, Jianchen ;
Quan, Baogang ;
Wei, Zhixiang .
MACROMOLECULAR RAPID COMMUNICATIONS, 2009, 30 (11) :936-940
[44]   Synthesis of electromagnetic functionalized nickel/polypyrrole core/shell composites [J].
Xu, Ping ;
Han, Xijiang ;
Wang, Chao ;
Zhou, Donghua ;
Lv, Zushun ;
Wen, Aihua ;
Wang, Xiaohong ;
Zhang, Bin .
JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (34) :10443-10448
[45]   Toward innovations of gas sensor technology [J].
Yamazoe, N .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 108 (1-2) :2-14
[46]   Electrocatalytic oxidation of methanol on polypyrrole film modified with platinum microparticles [J].
Yang, H ;
Lu, TH ;
Xue, KH ;
Sun, SG ;
Lu, GQ ;
Chen, SP .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (07) :2302-2307
[47]   One-pot fabrication of uniform polypyrrole/Au nanocomposites and investigation for gas sensing [J].
Zhang, Jun ;
Liu, Xianghong ;
Wu, Shihua ;
Xu, Hongyan ;
Cao, Bingqiang .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 186 :695-700
[48]   Reactive Template Synthesis of Polypyrrole Nanotubes for Fabricating Metal/Conducting Polymer Nanocomposites [J].
Zhang, Jun ;
Liu, Xianghong ;
Zhang, Lixue ;
Cao, Bingqiang ;
Wu, Shihua .
MACROMOLECULAR RAPID COMMUNICATIONS, 2013, 34 (06) :528-532
[49]   Polypyrrole-Coated SnO2 Hollow Spheres and Their Application for Ammonia Sensor [J].
Zhang, Jun ;
Wang, Shurong ;
Xu, Mijuan ;
Wang, Yan ;
Xia, Huijuan ;
Zhang, Shoumin ;
Guo, Xianzhi ;
Wu, Shihua .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (05) :1662-1665
[50]   Interaction between Palladium Microparticles and Polyaniline in Electrocatalytic Process for Oxidation of Formic Acid [J].
Zhong Qiling ;
Wu Wen ;
Li Wuhu ;
Tian Zhongqun .
ACTA PHYSICO-CHIMICA SINICA, 1994, 10 (09) :813-817