Preparation and characterization of the dicarbon cluster complex Ru-5(mu(5)-C-2)(mu-SMe)(2)(mu-PBu(2))(2)(CO)(11)

被引：5

作者：

Adams, CJ

Bruce, MI

机构：

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1996年 / 49卷 / 04期

关键词：

D O I：

10.1071/CH9960517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of the bis-tertiary phosphine C-2(PBu(2))(2) (dpba) is described. Pyrolysis of the ruthenium carbonyl derivative {Ru-3(CO)(11}?2(mu-dbpa) gives Ru-5(mu(5)-C(2)PBu(2))(mu-PBu(2))(CO)(13) [in 41% overall yield from Ru-3(CO)(12))] which in turn reacts with Me(2)S(2) to give Ru-5(mu(5)-C-2)(mu-SMe)(2)(mu-PBu(2))(2)(CO)(11) (19%).

引用

页码：517 / 520

页数：4

共 50 条

[41] ORGANIC-CHEMISTRY OF DINUCLEAR METAL CENTERS .6. MU-VINYLIDENE AND MU-ETHYLIDYNE DIRUTHENIUM COMPLEXES - CRYSTAL-STRUCTURES OF CIS-[RU2(CO)2(MU-CO)(MU-CCH2)(ETA-C5H5)2] AND CIS-[RU2(CO)2(MU-CO)(MU-CME)(ETA-C5H5)2][BF4]
COLBORN, RE
DAVIES, DL
DYKE, AF
ENDESFELDER, A
KNOX, SAR
ORPEN, AG
PLAAS, D
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (12): : 2661 - 2668
[42] CLUSTER CHEMISTRY .83. REACTIONS OF RU5(MU-5-C2PPH2)(MU-PPH2)(CO)13 WITH OLEFINS - PRODUCTS FORMED BY ADDITION OF AN ALKENE TO THE C2 FRAGMENT - X-RAY STRUCTURES OF RU5(MU-4-PPH)(MU-4-C2(CHCHR)CHCH2R)(MU-PPH2)-(CO)12(R = H, ME) AND RU5(MU-4-PPH)(MU-PPH2)(MU-CO)(CO)10-(ETA-5-C5H3ME-1-(CH=CH2)-3)
ADAMS, CJ
BRUCE, MI
LIDDELL, MJ
TIEKINK, ERT
SKELTON, BW
WHITE, AH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 445 (1-2) : 187 - 198
[43] POLYHEDRAL CLUSTER-EXPANSION IN [CO-3(CO)(6)[MU(2)-ETA(2)ETA(1)-C(PH)C=C(PPH(2))C(O)OC(O)](MU(2)-PPH(2)) - CHARACTERIZATION OF THE HYPHO CLUSTER CO-3(CO)(5)(MU-CO)(PME(3))[MU(2)-ETA(2)ETA(1)-C(PH)C=C(PPH(2))C(O)OC(O)]-(MU(2)-PPH(2)) AND THE PHOSPHINE-SUBSTITUTED ARACHNO CLUSTER CO-3(CO)(5)(PME(3))[MU(2)-ETA(2)ETA(1)-C(PH)C=C(PPH(2))C(O)OC(O)](MU(2)-PPH(2))
YANG, KY
BOTT, SG
RICHMOND, MG
ORGANOMETALLICS, 1995, 14 (02) : 919 - 924
[44] SYNTHESIS OF PHOSPHIDO-BRIDGED RUTHENIUM MANGANESE COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF (RUMN(MU-H)(MU-PPH2)-(ETA-5-C5H5)(CO)5), (RU2(MU-H)(MU-PPH2)(ETA-5-C5H5)2(CO)2) AND (RUMN2(MU-H)(MU-PPH2)2(ETA-5-C5H5)(CO)9)
CAFFYN, AJM
MAYS, MJ
RAITHBY, PR
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (09): : 2349 - 2356
[45] Synthesis and characterisation of the novel mixed-metal cluster [Ru5Rh(CO)(12)(mu-CO)(mu(4)-eta(2)-CO)(2)(eta(5)-C(5)Me(5))]
Davies, JE
Nahar, S
Raithby, PR
Shields, GP
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (01): : 13 - 14
[46] Reactions of dinuclear and polynuclear complexes .15. Reinvestigation of the reaction between [CpMo(CO)(3)H], allyl chloride and dimethyl disulfide: Crystal structure of [(C5H5)Mo(CO)(mu-SMe)(3)Mo(CO)(2)(mu-SMe)Mo(CO)(2)(C5H5)]
PoderGuillou, S
Schollhammer, P
Petillon, FY
Talarmin, J
Girdwood, SE
Muir, KW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 506 (1-2) : 321 - 326
[47] Metal substitution reaction in the cluster (mu-H)(2)Fe-3(mu(3)-Se)(CO)(9) .4. Crystal and molecular structure of [Fe2W2(mu(3)-Se)(2)(mu(3)-CO)(mu-CO)(CO)(5)(eta(5)-C5H5)(2)]
Konchenko, SN
Virovets, AV
Podberezskaya, NV
POLYHEDRON, 1997, 16 (10) : 1689 - 1691
[48] TRANSFORMATIONS OF MU-METHYLENE-DIRUTHENIUM COMPLEXES INTO TETRANUCLEAR METAL-CLUSTERS WITH MU--4-METHYLIDYNE AND MU-4-CARBIDO GROUPS - X-RAY CRYSTAL-STRUCTURES OF [RU2PT2(MU-H)(MU-4-CH)(MU-CO)(CO)2(PPRI3)2(ETA-C5H5)2] AND [RU2PT2(MU-H)2(MU-4-C)(MU-CO)2(PPRI3)2(ETA-C5H5)2]
DAVIES, DL
JEFFERY, JC
MIGUEL, D
SHERWOOD, P
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (06) : 454 - 456
[49] PHOTOCHEMICAL-REACTION OF MU-ETHENYLIDENE COMPLEX [(C5H5)(CO)FE]2(MU-CO)(MU-C=CH2) WITH ACETYLENES
CASEY, CP
MILES, WH
FAGAN, PJ
HALLER, KJ
ORGANOMETALLICS, 1985, 4 (03) : 559 - 563
[50] THE SYNTHESIS AND CHARACTERIZATION OF RU(6)(MU(3)-H)(MU(4)-ETA(2)-CO)(2)(CO)(13)(ETA(5)-C(5)H(4)ME) - AN EXAMPLE OF CLUSTER MEDIATED RING CONTRACTION
INGHAM, SL
JOHNSON, BFG
MARTIN, CM
PARKER, D
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (02) : 159 - 160

← 1 2 3 4 5 →