Preparation and characterization of the dicarbon cluster complex Ru-5(mu(5)-C-2)(mu-SMe)(2)(mu-PBu(2))(2)(CO)(11)

被引：5

作者：

Adams, CJ

Bruce, MI

机构：

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1996年 / 49卷 / 04期

关键词：

D O I：

10.1071/CH9960517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of the bis-tertiary phosphine C-2(PBu(2))(2) (dpba) is described. Pyrolysis of the ruthenium carbonyl derivative {Ru-3(CO)(11}?2(mu-dbpa) gives Ru-5(mu(5)-C(2)PBu(2))(mu-PBu(2))(CO)(13) [in 41% overall yield from Ru-3(CO)(12))] which in turn reacts with Me(2)S(2) to give Ru-5(mu(5)-C-2)(mu-SMe)(2)(mu-PBu(2))(2)(CO)(11) (19%).

引用

页码：517 / 520

页数：4

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