Effect of Temperature and a Non-Solvent Addition on the Specific Volume of Poly (Sodium-4-Styrene Sulfonate) in Water

被引:1
|
作者
Zoghlami, Ons [1 ]
Guettari, Moez [1 ]
Tajouri, Tahar [1 ]
机构
[1] Univ Tunis, NMR Polymers & Composites Lab, Preparatory Inst Engn Studies Tunis, Tunis, Tunisia
来源
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS | 2016年 / 55卷 / 12期
关键词
poly (sodium 4-styrene sulfonate); refractive index increment; solvent-non-solvent mixture; specific volume; REFRACTIVE-INDEX INCREMENT; POLY(SODIUM 4-STYRENE-SULFONATE); MOLECULAR-WEIGHT; AQUEOUS-SOLUTION; POLYELECTROLYTE; DEPENDENCE; SOLVENTS; POLYVINYLPYRROLIDONE; DIMENSIONS; SCATTERING;
D O I
10.1080/00222348.2016.1256182
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of temperature and a non-solvent, ethanol, addition on the specific volume of poly (sodium 4-styrene sulfonate) in water was investigated. The refractive indices of the studied solutions were measured over the 298.15-323.15K temperature range. Then, the specific volumes of the polyelectrolyte were calculated according to the Lorentz-Lorenz and Gladstone-Dale equations. The relative deviations of the specific volumes between measured and calculated according to these equations did not exceed 2.5%. Several empirical equations were deduced to describe the variations of the refractive index increment and the specific volume versus the temperature and the mixture composition.
引用
收藏
页码:1173 / 1188
页数:16
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