Hydrothermal synthesis and characterization of a new three-dimensional hybrid zinc phosphate [Zn2(HPO4)2(4,4′-bipy)]•3H2O with neutral porous framework

被引：15
作者：
Wang, L [1 ]
Yang, M [1 ]
Li, GH [1 ]
Shi, Z [1 ]
Feng, SH [1 ]
机构：
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2006年 / 179卷 / 01期
基金：
中国国家自然科学基金;
关键词：
hybrid compound; neutral framework; hydrothermal synthesis; zinc phosphate; crystal structure;
D O I：
10.1016/j.jssc.2005.10.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Employing 4,4'-bipyridine as a bridged ligand, a new three-dimensional (3-D) hybrid zinc phosphate [Zn-2(HPO4)(2)(4,4'-bipy)] (.) 3H(2)O has been prepared under hydrothermal conditions and characterized by single crystal X-ray diffraction. This compound crystallizes in the monoclinic space group C2/c, with cell parameters, a = 21.188(4)angstrom, b = 10.229(2)angstrom, c = 9.0656(18)angstrom, beta = 90.21(3)degrees, V = 1964.8(7)angstrom(3) and Z = 4. The connectivity of the ZnO3N and HPO4 tetrahedra results in a 2-D neutral layer that with interesting 4,8(2) net along the bc plane. Furthermore, the 4,4'-bipyridine molecule links the 4,8(2) net into a 3-D structure. The water molecules sit in the middle of the channels and interact with the framework via hydrogen bonds. The compound exhibits intense photoluminescence at room temperature. (c) 2005 Elsevier Inc. All rights reserved.
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页码：156 / 160
页数：5
相关论文
共 29 条
[1]  
[Anonymous], 1996, SMART SAINT
[2]  
Batrten S. R., 1998, ANGEW CHEM INT EDIT, V37, P1460
[3]   BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].
BROWN, ID ;
ALTERMATT, D .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247
[4]   Synthesis and characterization of organic-inorganic hybrid compounds with a pillared layer structure:: Ga2(4,4′-bpy)(XO4)2 (X = P, As) [J].
Chen, CY ;
Lii, KH ;
Jacobson, AJ .
JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (02) :252-256
[5]   Hydrothermal syntheses and crystal structures of complex-linked three-dimensional coordination vanadium selenites:: M(4,4′-bipy)(H2O)V2Se2O10 (M= Co, Ni) [J].
Dai, ZM ;
Chen, XB ;
Shi, Z ;
Zhang, D ;
Li, GH ;
Feng, SH .
INORGANIC CHEMISTRY, 2003, 42 (03) :908-912
[6]   A hydrothermal investigation of the 1/2V2O5-H2C2O4/H3PO4/NH4OH system:: Synthesis and structures of (NH4)VOPO4•1.5H2O, (NH4)0.5VOPO4•1.5H2O, (NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2]2•3H2O, and (NH4)2[VO(HPO4)]2(C2O4)•5H2O [J].
Do, J ;
Bontchev, RP ;
Jacobson, AJ .
INORGANIC CHEMISTRY, 2000, 39 (15) :3230-3237
[7]   New zinc phosphates decorated by imidazole-containing ligands [J].
Fan, J ;
Slebodnick, C ;
Angel, R ;
Hanson, BE .
INORGANIC CHEMISTRY, 2005, 44 (03) :552-558
[8]   New materials in hydrothermal synthesis [J].
Feng, SH ;
Xu, RR .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :239-247
[9]   LOW-TEMPERATURE SYNTHESIS OF HYDRATED ZINCO(BERYLLO)-PHOSPHATE AND ARSENATE MOLECULAR-SIEVES [J].
GIER, TE ;
STUCKY, GD .
NATURE, 1991, 349 (6309) :508-510
[10]  
Halasyamani PS, 1997, CHEM COMMUN, P867
123