Porous Cd-carboxylate frameworks tuned by the bulk of linker: Interpenetrated nets, selective CO2 uptakes and high water vapor adsorption

被引：6

作者：

Wang, Xing-Xia ^{[1
]}

Zhai, Quan-Guo ^{[1
]}

Li, Shu-Ni ^{[1
]}

Jiang, Yu-Cheng ^{[1
]}

Hu, Man-Cheng ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷

基金：

中国国家自然科学基金;

关键词：

MOFs; Interpenetrated nets; CO2; adsorption; Water vapor uptake; METAL-ORGANIC FRAMEWORKS; GAS-SORPTION PROPERTIES; COORDINATION POLYMERS; CARBON-DIOXIDE; 3D NET; CONSTRUCTION; TOPOLOGIES; LIGANDS; 2D;

D O I：

10.1016/j.inoche.2015.10.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reported herein are two porous interpenetrated anionic Cd-carboxylate frameworks tuned by the length of organic linker. Shorter BDC linker and [Cd(COO)(4)] building blocks in 1 generate a rare 4-connected 2-fold interpenetrating qtz network But longer NDC linker in 2 produces a self-penetrated 8-connected bcu framework with [Cd-3(COO)(8)] SBUs. 1 and 2 both show selective CO2 adsorption and significantly, 2 exhibits the highest water vapor uptake performance (281 cm(3).g(-1) at 298K and P/P-0 = 0.95) among all the interpenetrated MOFs. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：200 / 203

页数：4

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