The Nature of Hydrogen Bonding in Protic Ionic Liquids

被引：215

作者：

Hayes, Robert ^{[1
]}

Imberti, Silvia ^{[2
]}

Warr, Gregory G. ^{[3
]}

Atkin, Rob ^{[1
]}

机构：

[1] Univ Newcastle, Discipline Chem, Callaghan, NSW 2308, Australia

[2] Rutherford Appleton Lab, STFC, Didcot OX11 0QX, Oxon, England

[3] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 17期

关键词：

hydrogen bonds; ionic liquids; nanostructure; neutron diffration; self-assembly; X-RAY-DIFFRACTION; CRYSTAL-STRUCTURES; NONCOVALENT INTERACTIONS; STATISTICAL-ANALYSIS; ANION GROUPS; NITRATE; NANOSTRUCTURE; AMMONIUM; TEMPERATURE; PHASE;

D O I：

10.1002/anie.201209273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The size, direction, strength, and distribution of hydrogen bonds in several protic ionic liquids (PILs) has been elucidated using neutron diffraction and computer simulation. There is significant variation in PIL hydrogen bond interactions ranging from short and linear to long and bi-/trifurcated. The nature of the PIL's hydrogen bonds reflects its macroscopic properties. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4623 / 4627

页数：5

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