Enzyme-mediated syntheses of the enantiomers of γ-irones

被引：0

作者：

Brenna, E ^{[1
]}

Fuganti, C ^{[1
]}

Ronzani, S ^{[1
]}

Serra, S ^{[1
]}

机构：

[1] CNR, Ctr Studio Sostanze Organ Nat, Dipartimento Chim Politecn, I-20131 Milan, Italy

来源：

HELVETICA CHIMICA ACTA | 2001年 / 84卷 / 12期

关键词：

D O I：

10.1002/1522-2675(20011219)84:12<3650::AID-HLCA3650>3.0.CO;2-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An enzymatic approach to the synthesis of all the possible stereoisomers of (E) and (Z), cis and trans-gamma-irones in enantiomerically pure form from commercial Irone Alpha((R)) is described. A very efficient resolution of racemic trans-gamma-irone, affording both the enantiomers in high ee and chemical purity, is also presented. Olfactory evaluation of (+)- and (-)-3b and full configuration assignment of the irone isomers contained in samples of Italian iris oil are reported.

引用

页码：3650 / 3666

页数：17

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