Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis .2. Incubation and interpretation

被引:13
作者
Baldwin, JE [1 ]
Adlington, RM [1 ]
Marquess, DG [1 ]
Pitt, AR [1 ]
Porter, MJ [1 ]
Russell, AT [1 ]
机构
[1] OXFORD CTR MOLEC SCI,OXFORD OX1 3QY,ENGLAND
关键词
D O I
10.1016/0040-4020(95)01072-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Evidence to support an insertion-homolysis mechanism for the event leading to carbon-sulphur bond formation in penicillin biosynthesis has been obtained by incubation of a series of cyclopropane-containing stereochemical probes.
引用
收藏
页码:2537 / 2556
页数:20
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