Conducting metallophthalocyanine 2D covalent organic frameworks: the role of central metals in controlling π-electronic functions

被引：133

作者：

Ding, Xuesong ^{[1
]}

Feng, Xiao ^{[1
]}

Saeki, Akinori ^{[2
]}

Seki, Shu ^{[2
]}

Nagai, Atsushi ^{[1
]}

Jiang, Donglin ^{[1
,3
]}

机构：

[1] Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4448787, Japan

[2] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[3] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Tokyo, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 71期

关键词：

TRIAZINE-BASED FRAMEWORKS; RETICULAR SYNTHESIS; CRYSTALLINE; PHTHALOCYANINES; FILMS; ZN; CO;

D O I：

10.1039/c2cc33929c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phthalocyanine covalent organic frameworks with different central metals are synthesized, and the AA-stacking structure of the 2D polymer sheets results in periodic phthalocyanine pi-columns. The central metals control the pi-electronic functions, including the improvement of light absorbance, the ease of carrier transport, and the photocurrent gain.

引用

页码：8952 / 8954

页数：3

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