Conducting metallophthalocyanine 2D covalent organic frameworks: the role of central metals in controlling π-electronic functions

被引：126
作者：
Ding, Xuesong [1 ]
Feng, Xiao [1 ]
Saeki, Akinori [2 ]
Seki, Shu [2 ]
Nagai, Atsushi [1 ]
Jiang, Donglin [1 ,3 ]
机构：
[1] Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4448787, Japan
[2] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[3] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Tokyo, Japan
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 71期
关键词：
TRIAZINE-BASED FRAMEWORKS; RETICULAR SYNTHESIS; CRYSTALLINE; PHTHALOCYANINES; FILMS; ZN; CO;
D O I：
10.1039/c2cc33929c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phthalocyanine covalent organic frameworks with different central metals are synthesized, and the AA-stacking structure of the 2D polymer sheets results in periodic phthalocyanine pi-columns. The central metals control the pi-electronic functions, including the improvement of light absorbance, the ease of carrier transport, and the photocurrent gain.
引用
收藏
页码：8952 / 8954
页数：3
相关论文
共 32 条
  • [1] Rational Extension of the Family of Layered, Covalent, Triazine-Based Frameworks with Regular Porosity
    Bojdys, Michael J.
    Jeromenok, Jekaterina
    Thomas, Arne
    Antonietti, Markus
    [J]. ADVANCED MATERIALS, 2010, 22 (19) : 2202 - +
  • [2] Covalent and Noncovalent Phthalocyanine-Carbon Nanostructure Systems: Synthesis, Photoinduced Electron Transfer, and Application to Molecular Photovoltaics
    Bottari, Giovanni
    de la Torre, Gema
    Guldi, Dirk M.
    Torres, Tomas
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6768 - 6816
  • [3] Internal Functionalization of Three-Dimensional Covalent Organic Frameworks
    Bunck, David N.
    Dichtel, William R.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) : 1885 - 1889
  • [4] Rapid Microwave Synthesis and Purification of Porous Covalent Organic Frameworks
    Campbell, Neil L.
    Clowes, Rob
    Ritchie, Lyndsey K.
    Cooper, Andrew I.
    [J]. CHEMISTRY OF MATERIALS, 2009, 21 (02) : 204 - 206
  • [5] Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene
    Colson, John W.
    Woll, Arthur R.
    Mukherjee, Arnab
    Levendorf, Mark P.
    Spitler, Eric L.
    Shields, Virgil B.
    Spencer, Michael G.
    Park, Jiwoong
    Dichtel, William R.
    [J]. SCIENCE, 2011, 332 (6026) : 228 - 231
  • [6] Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks
    Cote, Adrien P.
    El-Kaderi, Hani M.
    Furukawa, Hiroyasu
    Hunt, Joseph R.
    Yaghi, Omar M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) : 12914 - +
  • [7] Porous, crystalline, covalent organic frameworks
    Côté, AP
    Benin, AI
    Ockwig, NW
    O'Keeffe, M
    Matzger, AJ
    Yaghi, OM
    [J]. SCIENCE, 2005, 310 (5751) : 1166 - 1170
  • [8] An n-Channel Two-Dimensional Covalent Organic Framework
    Ding, Xuesong
    Chen, Long
    Honsho, Yoshihito
    Feng, Xiao
    Saenpawang, Oraphan
    Guo, Jingdong
    Saeki, Akinori
    Seki, Shu
    Irle, Stephan
    Nagase, Shigeru
    Parasuk, Vudhichai
    Jiang, Donglin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (37) : 14510 - 14513
  • [9] Synthesis of Metallophthalocyanine Covalent Organic Frameworks That Exhibit High Carrier Mobility and Photoconductivity
    Ding, Xuesong
    Guo, Jia
    Feng, Xiao
    Honsho, Yoshihito
    Guo, Jingdong
    Seki, Shu
    Maitarad, Phornphimon
    Saeki, Akinori
    Nagase, Shigeru
    Jiang, Donglin
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (06) : 1289 - 1293
  • [10] Doonan CJ, 2010, NAT CHEM, V2, P235, DOI [10.1038/nchem.548, 10.1038/NCHEM.548]
1234