UV-assisted surface modification of PET fiber for adhesion improvement

被引:55
作者
Liu, Xiang-Dong [1 ,2 ]
Sheng, De-Kun [1 ,2 ]
Gao, Xiu-Mei [1 ,2 ]
Li, Tong-Bing [1 ,2 ]
Yang, Yu-Ming [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
PET fiber; Surface modification; Adhesion improvement; Laminate; ALKALINE-HYDROLYSIS; POLYETHYLENE FIBERS; POLY(ETHYLENE-TEREPHTHALATE); ENZYMES; PLASMA; POLYMERS; FABRICS;
D O I
10.1016/j.apsusc.2012.09.107
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile and highly efficient method for adhesion improvement of PET/TPU laminates was introduced. A considerable improvement in adhesion was achieved by treating PET fabric with isocyanate (MDI) in toluene solution. Compared with unmodified ones, the maximal peel strength reaches to 2.27 kN/m (up to three times). The fabrics were also treated with NaOH and CDT (corona discharge treatment) and the results were compared respectively. It is considered that the improvement mainly depends on the strengthening of chemical bonding and mechanical interlocking between the fiber and the adhesive matrix. As the difference directly affects the effective transference of the stress (tension force) from matrix to fiber. The failure surface of PET fiber was severely destroyed which could be examined by scanning electron microscopy (SEM). Published by Elsevier B.V.
引用
收藏
页码:61 / 69
页数:9
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