Synthesis of precursors of the agalacto (exo) fragment of the quartromicins via an auxiliary-controlled exo-selective Diels-Alder reaction

被引：29
|
作者：
Qi, Jun [1 ]
Roush, William R.
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
[2] Scripps Florida, Dept Chem, Jupiter, FL 33458 USA
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 13期
关键词：
D O I：
10.1021/ol0609208
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A direct synthesis of the alpha-hydroxyaldehyde exo-5, a precursor of the exo-spirotetronate subunit of the quartromicins, was achieved through an exo-selective Lewis acid-catalyzed Diels-Alder reaction of dienophile 12a and diene 1.
引用
收藏
页码：2795 / 2798
页数：4
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