Fluorinated electrolytes for 5 V lithium-ion battery chemistry

被引：498
作者：
Zhang, Zhengcheng [1 ]
Hu, Libo [1 ]
Wu, Huiming [1 ]
Weng, Wei [1 ]
Koh, Meiten [3 ]
Redfern, Paul C. [2 ]
Curtiss, Larry A. [2 ]
Amine, Khalil [1 ,4 ]
机构：
[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA
[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
[3] Daikin Ind Ltd, Settsu, Osaka, Japan
[4] King Abdulaziz Univ, Jeddah 21413, Saudi Arabia
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2013年 / 6卷 / 06期
关键词：
SULFONE-BASED ELECTROLYTES; FLUOROETHYLENE CARBONATE; CATHODE; PERFORMANCE; STABILITY; DINITRILE; LIQUIDS;
D O I：
10.1039/c3ee24414h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An electrolyte based on fluorinated carbonate solvents was evaluated with high voltage cathode materials at elevated temperature. The theoretically high anodic stability of these new electrolytes was supported by electrochemical evaluation results using LiNi0.5Mn1.5O4/Li and LiNi0.5Mn1.5O4/Li4Ti5O12 electrochemical couples. Fluorinated carbonate appears to be a suitable electrolyte candidate for transition metal oxide cathodes at high voltage (5 V vs. Li+/Li).
引用
收藏
页码：1806 / 1810
页数：5
相关论文
共 34 条
  • [1] Sulfone-based electrolytes for high-voltage Li-ion batteries
    Abouimrane, A.
    Belharouak, I.
    Amine, K.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (05) : 1073 - 1076
  • [2] High-Voltage Electrolytes Based on Adiponitrile for Li-Ion Batteries
    Abu-Lebdeh, Yaser
    Davidson, Isobel
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (01) : A60 - A65
  • [3] New electrolytes based on glutaronitrile for high energy/power Li-ion batteries
    Abu-Lebdeh, Yaser
    Davidson, Isobel
    [J]. JOURNAL OF POWER SOURCES, 2009, 189 (01) : 576 - 579
  • [4] Thermal Stability and Electrochemical Properties of Fluorine Compounds as Nonflammable Solvents for Lithium-Ion Batteries
    Achiha, Takashi
    Nakajima, Tsuyoshi
    Ohzawa, Yoshimi
    Koh, Meiten
    Yamauchi, Akiyoshi
    Kagawa, Michiru
    Aoyama, Hirokazu
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (06) : A707 - A712
  • [5] Electrochemical Behavior of Nonflammable Organo-Fluorine Compounds for Lithium Ion Batteries
    Achiha, Takashi
    Nakajima, Tsuyoshi
    Ohzawa, Yoshimi
    Koh, Meiten
    Yamauchi, Akiyoshi
    Kagawa, Michiru
    Aoyama, Hirokazu
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (06) : A483 - A488
  • [6] [Anonymous], 2006, J ELECTROCHEM SOC
  • [7] Building better batteries
    Armand, M.
    Tarascon, J. -M.
    [J]. NATURE, 2008, 451 (7179) : 652 - 657
  • [8] On the application of ionic liquids for rechargeable Li batteries: High voltage systems
    Borgel, V.
    Markevich, E.
    Aurbach, D.
    Semrau, G.
    Schmidt, M.
    [J]. JOURNAL OF POWER SOURCES, 2009, 189 (01) : 331 - 336
  • [9] Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode
    Choi, Nam-Soon
    Yew, Kyoung Han
    Lee, Kyu Youl
    Sung, Minseok
    Kim, Ho
    Kim, Sung-Soo
    [J]. JOURNAL OF POWER SOURCES, 2006, 161 (02) : 1254 - 1259
  • [10] Effect of Added LiBOB on High Voltage (LiNi0.5Mn1.5O4) Spinel Cathodes
    Dalavi, Swapnil
    Xu, Mengqing
    Knight, Brandon
    Lucht, Brett L.
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2012, 15 (02) : A28 - A31
1234