The influence of injection molding parameters on electrical properties of PC/ABS-MWCNT nanocomposites

被引:22
作者
Wegrzyn, Marcin [1 ]
Juan, Sara [1 ]
Benedito, Adolfo [1 ]
Gimenez, Enrique [2 ]
机构
[1] Inst Tecnol Plast AIMPLAS, Paterna 46980, Spain
[2] Univ Politecn Valencia, Inst Tecnol Mat, Valencia 46022, Spain
关键词
blends; thermoplastics; nanotubes; graphene and fullerenes; microscopy; CARBON NANOTUBE; POLYCARBONATE; CONDUCTIVITY; RESISTIVITY; COMPOSITES; AGGLOMERATION; SPECTROSCOPY; NETWORK;
D O I
10.1002/app.39412
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The influence of injection molding parameters on electrical properties and morphology of PC/ABS-MWCNT nanocomposites is presented in this article. Investigation is based on the masterbatch of 5.0wt% carbon nanotubes obtained by melt-mixing. Further processing includes dilution of this nanocomposite to desired concentrations on twin-screw extruder and injection molding or direct dilution of masterbatch in injection molding. Additionally, reprocessing of materials formed by compression and injection molding is presented along with the change in electrical conductivity. Morphology differs strongly between the two processing paths showing change in agglomeration behavior between nanotubes concentrations. Electrical properties show dependence on injection velocity and melt temperature in both applied processing paths. Moreover, electrical conductivity recovery is proved after injection and compression molding. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2152-2158, 2013
引用
收藏
页码:2152 / 2158
页数:7
相关论文
共 21 条
  • [1] Destruction and formation of a conductive carbon nanotube network in polymer melts:: In-line experiments
    Alig, Ingo
    Lellinger, Dirk
    Engel, Martin
    Skipa, Tetyana
    Poetschke, Petra
    [J]. POLYMER, 2008, 49 (07) : 1902 - 1909
  • [2] Chandra A., 2007, P ANN TECHN C SOC PL, V3, P2184
  • [3] Conductivity enhancement of carbon nanotube and nanofiber-based polymer nanocomposites by melt annealing
    Cipriano, Bani H.
    Kota, Arun K.
    Gershon, Alan L.
    Laskowski, Conrad J.
    Kashiwagi, Takashi
    Bruck, Hugh A.
    Raghavan, Srinivasa R.
    [J]. POLYMER, 2008, 49 (22) : 4846 - 4851
  • [4] Morphology Effects on Nonisotropic Thermal Conduction of Aligned Single-Walled and Multi-Walled Carbon Nanotubes in Polymer Nanocomposites
    Duong, Hai M.
    Yamamoto, Namiko
    Bui, Khoa
    Papavassiliou, Dimitrios V.
    Maruyama, Shigeo
    Wardle, Brian L.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (19) : 8851 - 8860
  • [5] Kasaliwal G. R., 2011, POLYM CARBON NANOTUB
  • [6] Influence of small scale melt mixing conditions on electrical resistivity of carbon nanotube-polyamide composites
    Krause, Beate
    Poetschke, Petra
    Haeussler, Liane
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (10) : 1505 - 1515
  • [7] Effects of filler geometry on internal structure and physical properties of polycarbonate composites prepared with various carbon fillers
    Lee, Seung Hwan
    Kim, Jong Hyuk
    Kim, Kyeong Wung
    Youn, Jae Ryoun
    Choi, Sheong Hyun
    Kim, Seong Yun
    [J]. POLYMER INTERNATIONAL, 2009, 58 (04) : 354 - 361
  • [8] Influence of the injection moulding conditions on the in-line measured electrical conductivity of polymer-carbon nanotube composites
    Lellinger, Dirk
    Xu, Donghua
    Ohneiser, Alexander
    Skipa, Tetyana
    Alig, Ingo
    [J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2008, 245 (10): : 2268 - 2271
  • [9] Lew C. Y., 2011, POLYM CARBON NANOTUB
  • [10] Morphological manipulation of carbon nanotube/polycarbonate/polyethylene composites by dynamic injection packing molding
    Li, Sha-Ni
    Li, Bo
    Li, Zhong-Ming
    Fu, Qiang
    Shen, Kai-Zhi
    [J]. POLYMER, 2006, 47 (13) : 4497 - 4500