Assembly of a new Keggin polyoxometalate-templated complex using flexible 1,2-bis(imidazol-1′-yl)ethane ligand

被引：9
作者：
Wu, Jiang [1 ]
Xu, Yanglei [1 ]
Yu, Kai [1 ]
Su, Zhanhua [1 ]
Zhou, Baibin [1 ]
机构：
[1] Harbin Normal Univ, Key Lab Synth Funct Mat & Green Catalysis, Coll Heilongjiang Prov, Harbin, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 16期
基金：
中国国家自然科学基金;
关键词：
Keggin-type polyoxometalates; Copper; Flexibility; Electrochemical property; ELECTROCHEMICAL PROPERTIES; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMER; CLUSTERS; POM; POLYOXOTUNGSTATES; HETEROPOLY; CHEMISTRY;
D O I：
10.1080/00958972.2013.817571
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound, [{Cu-I(bim)}(4){SiW12O40}] (1) (bim=1,2-bis(imidazol-1-yl)ethane), was hydrothermally synthesized and characterized by elemental analyses, IR, TG, and single-crystal X-ray diffraction. Compound 1 is an infinite 1-D chain composed of Cu-bim coordination polymers and [-SiW12O40](4-) polyanions. The electrochemical and electrocatalytic behaviors of 1-modified carbon paste electrode (1-CPE) have been studied.
引用
收藏
页码：2821 / 2828
页数：8
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