Assembly of a new Keggin polyoxometalate-templated complex using flexible 1,2-bis(imidazol-1′-yl)ethane ligand

被引：9

作者：

Wu, Jiang ^{[1
]}

Xu, Yanglei ^{[1
]}

Yu, Kai ^{[1
]}

Su, Zhanhua ^{[1
]}

Zhou, Baibin ^{[1
]}

机构：

[1] Harbin Normal Univ, Key Lab Synth Funct Mat & Green Catalysis, Coll Heilongjiang Prov, Harbin, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 16期

基金：

中国国家自然科学基金;

关键词：

Keggin-type polyoxometalates; Copper; Flexibility; Electrochemical property; ELECTROCHEMICAL PROPERTIES; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMER; CLUSTERS; POM; POLYOXOTUNGSTATES; HETEROPOLY; CHEMISTRY;

D O I：

10.1080/00958972.2013.817571

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new compound, [{Cu-I(bim)}(4){SiW12O40}] (1) (bim=1,2-bis(imidazol-1-yl)ethane), was hydrothermally synthesized and characterized by elemental analyses, IR, TG, and single-crystal X-ray diffraction. Compound 1 is an infinite 1-D chain composed of Cu-bim coordination polymers and [-SiW12O40](4-) polyanions. The electrochemical and electrocatalytic behaviors of 1-modified carbon paste electrode (1-CPE) have been studied.

引用

页码：2821 / 2828

页数：8

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