Syntheses, Structures, Luminescence and Magnetic Properties of Three New Metal-organic Frameworks Based on Rigid Carbazole Ligand

被引：0

作者：

Xue Jun-Ru ^{[1
]}

He Zhan ^{[1
]}

Zhang Shu-Fang ^{[1
]}

Liang Yue ^{[1
]}

Zhang Xia ^{[1
]}

Jing Lin-Hai ^{[1
]}

Qin Da-Bin ^{[1
]}

机构：

[1] China West Normal Univ, Sch Chem & Chem Engn, Key Lab Chem Synth & Pollut Control Sichuan Prov, Nanchong 637002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 35卷 / 10期

基金：

中国国家自然科学基金;

关键词：

metal-organic frameworks; carbazole; luminescence; GAS-ADSORPTION PROPERTIES; COORDINATION POLYMERS; CONSTRUCTION; SEPARATION; DIVERSITY; COMPLEXES; STORAGE; CD(II); MOFS; 2D;

D O I：

10.14102/j.cnki.0254-5861.2011-1090

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new metal-organic frameworks [Cd(L)(obba)].H2O (1), [Co(L)(obba)] . MeCN (2) and [Cd-2(L)(2)(ip)(2)].6H(2)O.DMF (3) (H(2)obba = 4,4'-oxybisbenzoic acid, H(2)ip = m-phthalic acid) have been successfully synthesized based on the controllable self-assembly of 9-ethyl-3,6diimidazolyl- carbazole (L), varied carboxylates and different metal ions under solvothermal conditions, which were characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetry. Furthermore, luminescence and magnetic susceptibility of compound 2 are also investigated in detail. Single-crystal X-ray diffraction and topology analysis reveal that complexes 1 similar to 3 exhibit similar two-dimensional (2D) networks.

引用

页码：1574 / 1581

页数：8

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