Syntheses, Structures, Luminescence and Magnetic Properties of Three New Metal-organic Frameworks Based on Rigid Carbazole Ligand

被引：0
|
作者：
Xue Jun-Ru [1 ]
He Zhan [1 ]
Zhang Shu-Fang [1 ]
Liang Yue [1 ]
Zhang Xia [1 ]
Jing Lin-Hai [1 ]
Qin Da-Bin [1 ]
机构：
[1] China West Normal Univ, Sch Chem & Chem Engn, Key Lab Chem Synth & Pollut Control Sichuan Prov, Nanchong 637002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 35卷 / 10期
基金：
中国国家自然科学基金;
关键词：
metal-organic frameworks; carbazole; luminescence; GAS-ADSORPTION PROPERTIES; COORDINATION POLYMERS; CONSTRUCTION; SEPARATION; DIVERSITY; COMPLEXES; STORAGE; CD(II); MOFS; 2D;
D O I：
10.14102/j.cnki.0254-5861.2011-1090
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new metal-organic frameworks [Cd(L)(obba)].H2O (1), [Co(L)(obba)] . MeCN (2) and [Cd-2(L)(2)(ip)(2)].6H(2)O.DMF (3) (H(2)obba = 4,4'-oxybisbenzoic acid, H(2)ip = m-phthalic acid) have been successfully synthesized based on the controllable self-assembly of 9-ethyl-3,6diimidazolyl- carbazole (L), varied carboxylates and different metal ions under solvothermal conditions, which were characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetry. Furthermore, luminescence and magnetic susceptibility of compound 2 are also investigated in detail. Single-crystal X-ray diffraction and topology analysis reveal that complexes 1 similar to 3 exhibit similar two-dimensional (2D) networks.
引用
收藏
页码：1574 / 1581
页数：8
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