The Capacity and Durability of Amorphous Silicon Nanotube Thin Film Anode for Lithium Ion Battery Applications

被引:9
作者
Carreon, Maria L. [1 ]
Thapa, Arjun K.
Jasinski, Jacek B.
Sunkara, Mahendra K.
机构
[1] Univ Louisville, Dept Chem Engn, Louisville, KY 40292 USA
基金
美国国家科学基金会;
关键词
ALLOY ANODES; NANOWIRES; ELECTRODE; PERFORMANCE; INSERTION; STORAGE; EXTRACTION; PARTICLES; COMPOSITE; LIFE;
D O I
10.1149/2.0031510eel
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this communication, we report that a silicon nanotube thin film electrode with 0.6 mg loading exhibited an initial discharge capacity of 4766 mAh g(-1) and retained about 3400 mAh g(-1) after 20.cycles at 100 mA g(-1) rate. The silicon nanotube thin film samples with thicknesses ranging from 10-28 microns were prepared using silicon deposition on bulk produced zinc oxide nanowire films and subsequent removal of zinc oxide cores. The developed silicon nanostructures exhibit tubular geometry with both open ends. The nanotubes with thin walls are shown to accommodate large volume changes with lithiation and exhibit stable capacity retention. The presence of hydrogenated nanocrystalline silicon (nc-Si:H) is shown to be essential for the silicon nanotube thin film performance for lithium ion battery applications. (C) The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved.
引用
收藏
页码:A124 / A128
页数:5
相关论文
共 32 条
  • [11] Synthesis of crystalline silicon tubular nanostructures with ZnS nanowires as removable templates[J]. Hu, JQ;Bando, Y;Liu, ZW;Zhan, JH;Golberg, D;Sekiguchi, T. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004(01)
  • [12] A new class of tailor-made Fe0.92Mn0.08Si2 lithium battery anodes:: Effect of composite and carbon coated Fe0.92Mn0.08Si2 anodes[J]. Jayaprakash, N.;Kalaiselvi, N.;Doh, C. H. INTERMETALLICS, 2007(03)
  • [13] CHANGE IN CRYSTALLINE MORPHOLOGIES OF POLYCRYSTALLINE SILICON FILMS PREPARED BY RADIOFREQUENCY PLASMA-ENHANCED CHEMICAL-VAPOR-DEPOSITION USING SIF4+H2 GAS-MIXTURE AT 350-DELTA-C[J]. KANEKO, T;WAKAGI, M;ONISAWA, K;MINEMURA, T. APPLIED PHYSICS LETTERS, 1994(14)
  • [14] Kawai Y., 2010, IND PLASMA TECHNOLOG
  • [15] Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries[J]. Kim, Hyunjung;Han, Byunghee;Choo, Jaebum;Cho, Jaephil. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008(52)
  • [16] Gas-Phase, Bulk Production of Metal Oxide Nanowires and Nanoparticles Using a Microwave Plasma Jet Reactor[J]. Kumar, Vivekanand;Kim, Jeong H.;Pendyala, Chandrashekhar;Chernomordik, Boris;Sunkara, Mahendra K. JOURNAL OF PHYSICAL CHEMISTRY C, 2008(46)
  • [17] The crystal structural evolution of nano-Si anode caused by lithium insertion and extraction at room temperature[J]. Li, H;Huang, XJ;Chen, LQ;Zhou, GW;Zhang, Z;Yu, DP;Mo, YJ;Pei, N. SOLID STATE IONICS, 2000(1-4)
  • [18] Electrochemically-driven solid-state amorphization in lithium-silicon alloys and implications for lithium storage[J]. Limthongkul, P;Jang, YI;Dudney, NJ;Chiang, YM. ACTA MATERIALIA, 2003(04)
  • [19] MoO3-x Nanowire Arrays As Stable and High-Capacity Anodes for Lithium Ion Batteries[J]. Meduri, Praveen;Clark, Ezra;Kim, Jeong H.;Dayalan, Ethirajulu;Sumanasekera, Gamini U.;Sunkara, Mahendra K. NANO LETTERS, 2012(04)
  • [20] Hybrid Tin Oxide Nanowires as Stable and High Capacity Anodes for Li-Ion Batteries[J]. Meduri, Praveen;Pendyala, Chandrashekhar;Kumar, Vivekanand;Sumanasekera, Gamin U.;Sunkara, Mahendra K. NANO LETTERS, 2009(02)