Merging tribenzotriquinacene with hexa-peri-hexabenzocoronene: a cycloheptatriene unit generated by Scholl reaction

被引：58
作者：
Mughal, Ehsan Ullah [1 ]
Kuck, Dietmar [1 ]
机构：
[1] Univ Bielefeld, Dept Chem, D-33615 Bielefeld, Germany
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 71期
关键词：
POLYCYCLIC AROMATIC-HYDROCARBONS; CARBON NANOTUBES; BUILDING-BLOCKS; DERIVATIVES; MECHANISM; ROUTE;
D O I：
10.1039/c2cc34245f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The single-wing extension of the bowl-shaped tribenzotriquinacene (TBTQ) framework with polycondensed aromatic hydrocarbon units has been reported. In the course of a Scholl reaction, one of the three-dimensional bays of the TBTQ core has been bridged by a PAH unit to generate a seven-membered ring within the merged TBTQ-(hexa-peri-hexabenzocoronene) scaffold.
引用
收藏
页码：8880 / 8882
页数：3
相关论文
共 61 条
[1]  
[Anonymous], 1987, Handbook of Polycyclic Hydrocarbons. Part A: Benzenoid Hydrocarbons
[2]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[3]  
Bhola R., 2011, 14 INT S NOV AR COMP
[4]   Carbon nanotubes by quantitative solid-state conversion of an organometallic precursor [J].
Burghard, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (48) :5929-5930
[5]   Discotic hexa-peri-hexabenzocoronenes with strong dipole: synthesis, self-assembly and dynamic studies [J].
Chen, Long ;
Dou, Xi ;
Pisula, Wojciech ;
Yang, Xiaoyin ;
Wu, Dongqing ;
Floudas, George ;
Feng, Xinliang ;
Muellen, Klaus .
CHEMICAL COMMUNICATIONS, 2012, 48 (05) :702-704
[6]   MP2 and DFT calculations on circulenes and an attempt to prepare the second lowest benzolog, [4]Circulene [J].
Christoph, Hilmar ;
Grunenberg, Joerg ;
Hopf, Henning ;
Dix, Ina ;
Jones, Peter G. ;
Scholtissek, Martin ;
Maier, Guenther .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (18) :5604-5616
[7]  
Clar E., 1952, Aromatische Kohlenwasserstoffe: Polycyclische Systeme
[8]  
Clar E., 1964, POLYCYCLIC HYDROCARB, VI
[9]  
COREY EJ, 1972, TETRAHEDRON LETT, P3769
[10]   SYNTHETIC APPROACHES TOWARD MOLECULAR AND POLYMERIC CARBON ALLOTROPES [J].
DIEDERICH, F ;
RUBIN, Y .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (09) :1101-1123
1234567