The relationship between microstructure and properties in PP/rubber powder/nano-CaCO3 ternary blends

被引:11
作者
Su, XQ
Hua, YQ [1 ]
Qiao, JL
Liu, YQ
Zhang, XH
Gao, JM
Song, ZH
Huang, F
Zhang, ML
机构
[1] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China
[2] SINOPEC Beijing Res Inst Chem Ind, Beijing 100013, Peoples R China
关键词
nano-CaCO3; poly(propylene); rubber powder; salami" structure; toughness;
D O I
10.1002/mame.200300209
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new kind of rubber powder with "salami" structure (RPS) was prepared by spray drying the mixture of styrene-butadiene rubber latex and nano-CaCO3 slurry. It was found that RPS is an effective toughener with synergistic toughening effect on poly(propylene) (PP). The Izod impact strength of PP/RPS blend is not only higher than that of PP/rubber powder or PP/nano-CaCO3 blends, but also higher than that of a PP/rubber powder/CaCO3 blend. TEM images show that the microstructure of the PP/RPS blend is an "island-sea" structure with "salami" structure in RPS, in which nano-CaCO3 particles are embedded in styrene-butadiene rubber particles. The relationship between properties and microstructure has been studied by using TEM, SEM, DSC, etc.
引用
收藏
页码:275 / 280
页数:6
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