Crystal and molecular structure of [N,N-bis(2-carbamoylethyl)amino-2-propionato]isothicyanatocopper(II) monohydrate, [Cu(Bceala)(NCS)] • H2O

被引：0

作者：

Polyakova, IN ^{[1
]}

Sergienko, VS ^{[1
]}

Poznyak, AL ^{[1
]}

机构：

[1] Belarussian Acad Sci, Inst Mol & Atom Phys, Minsk 220072, BELARUS

来源：

CRYSTALLOGRAPHY REPORTS | 1999年 / 44卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The X-ray crystal structure of [Cu(Bceala)(NCS)] . H2O, where HBceala is N,N-bis(2-carbamoylethyl)amino-2-propionic acid, is determined. The unit-cell parameters are a = 9.555(2), b = 10.815(2), and c = 14.877(3) Angstrom; Z = 4; and space group P2(1)2(1)2(1); R = 0.0363 for 1563 reflections with I > 2 sigma(I). A distorted tetragonal-pyramidal coordination of the Cu2+ atom is formed by three O atoms and the N atom of the tetradentate chelate ligand Bceala(-) and the N atom of the NCS- anion. The structure of the complex studied is compared with the structure of the copper(II) complex with N,N-bis(2-carbamoylethyl)aminoacetic acid, [Cu(Bcegly)(NCS)].

引用

页码：579 / 581

页数：3