Particle Formation in Vinyl Chloride Emulsion Polymerization. Experimental Study

被引：8
|
作者：
Vale, Hugo M. [1 ]
McKenna, Timothy F. L. [1 ]
机构：
[1] ESCPE Lyon, CNRS, LCPP, F-69616 Villeurbanne, France
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2008年 / 47卷 / 21期
关键词：
D O I：
10.1021/ie0715153
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Particle formation in vinyl chloride emulsion polymerization has been investigated by means of ab initio and seeded experiments. A series of ab initio polymerizations was run in order to obtain reliable data regarding the dependence of the particle number on the emulsifier (SDS and SDBS) concentration, as well as to analyze the effect of the initiator concentration, stirring rate, and monomer-to-water ratio upon the particle number and the polymerization kinetics. Seeded polymerizations carried out at different concentrations of seed latex and surfactant made it possible to quantitatlvely evaluate the influence of these factors on the onset and extent of secondary particle formation.
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页码：8107 / 8118
页数：12
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