Rare earth salt catalyzed asymmetric Diels-Alder reaction with a chiral dienophile in supercritical carbon dioxide: Enhancement effect on stereoselectivity

被引：0

作者：

Fukuzawa, SI ^{[1
]}

Metoki, K ^{[1
]}

Komuro, Y ^{[1
]}

Funazukuri, T ^{[1
]}

机构：

[1] Chuo Univ, Inst Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan

来源：

SYNLETT | 2002年 / 01期

关键词：

rare earth(III) salt; Diels-Alder; cyclopentadiene;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rare earth(III) salt catalyzed asymmetric Diels-Alder reaction of cyclopentadiene with a chiral dienophile in super-critical carbon dioxide (scCO(2)) proceeded rapidly to give the adduct with a higher diastereoselectivity than that in dichloromethane; optimization of the CO2 density increased the de value up to 77%.

引用

页码：134 / 136

页数：3

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