Influence of activated carbon surface oxygen functionalities on SO2 physisorption - Simulation and experiment

被引：31

作者：

Furmaniak, Sylwester ^{[1
]}

Terzyk, Artur P. ^{[1
]}

Gauden, Piotr A. ^{[1
]}

Kowalczyk, Piotr ^{[2
]}

Szymanski, Grzegorz S. ^{[1
]}

机构：

[1] Nicholas Copernicus Univ, Dept Chem, Physicochem Carbon Mat Res Grp, PL-87100 Torun, Poland

[2] Curtin Univ Technol, Dept Chem, Nanochem Res Inst, Perth, WA 6845, Australia

来源：

CHEMICAL PHYSICS LETTERS | 2013年 / 578卷

关键词：

POROUS CARBONS; ADSORPTION; WATER; THERMODYNAMICS; REMOVAL; GASES;

D O I：

10.1016/j.cplett.2013.05.060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of the gradual oxidation of carbons on SO2 physisorption was studied, by comparison of experimental and simulated SO2 adsorption isotherms. The results confirmed a significant impact of surface groups on the SO2 adsorption. The simulations also revealed a similar, to that observed experimentally, effect of the increase in the percentage of the smallest micropores on adsorption isotherms. The isotherms were analysed using the CMMS model. The conclusion is that this model seems to be a good and sensitive tool for studying SO2 physisorption mechanism since a very good qualitative agreement between the experimental and simulated data was observed. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：85 / 91

页数：7

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