Impact of different Nd-rich crystal-phases on the coercivity of Nd-Fe-B grain ensembles

被引:91
作者
Hrkac, G. [1 ,4 ]
Woodcock, T. G. [2 ]
Butler, K. T. [3 ]
Saharan, L.
Bryan, M. T. [4 ]
Schrefl, T. [5 ]
Gutfleisch, O. [2 ,6 ]
机构
[1] Univ Exeter, Coll Engn Math & Phys Sci, Exeter, Devon, England
[2] IFW Dresden, Inst Metall Mat, D-01171 Dresden, Germany
[3] Univ Bath, Ctr Sustainable Chem Technol, Bath BA2 7AY, Avon, England
[4] Univ Sheffield, Dept Engn Mat, Sheffield S1JD, S Yorkshire, England
[5] St Polten Univ Appl Sci, A-3100 St Polten, Austria
[6] Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany
关键词
Nd-Fe-B; Permanent magnet; Coercivity; Grain boundary; Lattice minimization; ANISOTROPY; MICROSTRUCTURE; CU;
D O I
10.1016/j.scriptamat.2013.08.029
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Aberration-corrected transmission electron microscopy, combined with atomistic simulations, has been used to study the anisotropy profiles of interfaces between metallic Nd (fcc, dhcp), Nd2O3 (hP5, cI80), NdO and the Nd2Fe14B phase. The results show that the dhcp Nd and Nd2O3-hP5 phases have a more detrimental effect on coercivity than fcc Nd, Nd2O3-c180 and NdO. The coercivity change is rooted in distortions in the Nd2Fe14B crystal lattice; the depth and magnitude of this change is a function of orientation and type of Nd-rich phase. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:35 / 38
页数:4
相关论文
共 25 条
[1]   MAGNETOSTRICTION IN HIGH PULSED MAGNETIC-FIELDS ON A SINGLE-CRYSTAL OF ND2FE14B [J].
ALGARABEL, PA ;
IBARRA, MR ;
MARQUINA, C ;
DELMORAL, A ;
ZEMIRLI, S .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1990, 84 (1-2) :109-114
[2]   REFINEMENT OF ND2O3 STRUCTURE AND DETERMINATION OF NEUTRON-SCATTERING LENGTH OF NEODYMIUM [J].
BOUCHERLE, JX ;
SCHWEIZER, J .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (NOV15) :2745-2746
[3]   VIRTUES AND WEAKNESSES OF THE DOMAIN CONCEPT [J].
BROWN, WF .
REVIEWS OF MODERN PHYSICS, 1945, 17 (01) :15-19
[4]   Atomistic study of the phase stability and site preference for Gd3(Fe,T)29 (T=V, Ti, Cr, Mo, Cu, Ag) [J].
Chen, NX ;
Shen, J ;
Wang, XL .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 359 (1-2) :91-98
[5]   Magnetoelastic anisotropy in NdFeB permanent magnets [J].
de Groot, CH ;
de Kort, K .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (12) :8312-8316
[6]   THEORY OF THE DIELECTRIC CONSTANTS OF ALKALI HALIDE CRYSTALS [J].
DICK, BG ;
OVERHAUSER, AW .
PHYSICAL REVIEW, 1958, 112 (01) :90-103
[7]   Microstructure and magnetic effects of small Cu additions to (Nd,Dy)FeB magnets [J].
Engelmann, HJ ;
Kim, AS ;
Thomas, G .
SCRIPTA MATERIALIA, 1997, 36 (01) :55-62
[8]   ELECTRON-MICROSCOPY OF ND-FE-B BASED MAGNETS [J].
FIDLER, J ;
KNOCH, KG .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1989, 80 (01) :48-56
[9]   GULP: Capabilities and prospects [J].
Gale, JD .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2005, 220 (5-6) :552-554
[10]   Controlling the properties of high energy density permanent magnetic materials by different processing routes [J].
Gutfleisch, O .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2000, 33 (17) :R157-R172