Chemical polymerization of aniline in the presence of mixtures of polymeric sulfonic acids

被引：0

作者：

Omel'chenko, O. D. ^{[1
]}

Gribkova, O. L. ^{[1
]}

Nekrasov, A. A. ^{[1
]}

Ivanov, V. F. ^{[1
]}

Kravchenko, V. V. ^{[2
]}

Vannikov, A. V. ^{[1
]}

Tverskoi, V. A. ^{[2
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia

[2] Moscow Univ Fine Chem Technol, Moscow 119571, Russia

来源：

POLYMER SCIENCE SERIES B | 2013年 / 55卷 / 3-4期

基金：

俄罗斯基础研究基金会;

关键词：

MISCIBLE BLENDS; POLYANILINE; COMPLEXES;

D O I：

10.1134/S1560090413040064

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The template polymerization of aniline in the presence of polymeric sulfonic acids of various structures and their mixtures is studied. In the latter case, the dominant effect of a polyacid on the kinetics of aniline polymerization and the electronic structure of the resulting polyaniline complex is observed. As shown by viscometry measurements and IR studies, the intermolecular interaction between polyacids in their mixtures that leads to a change in the conformation of a flexible-chain polyacid is responsible for the dominant effect of a rigid-chain polyacid. The spectral and electrical properties of polyaniline-based interpolymer complexes are examined.

引用

页码：187 / 194

页数：8

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