Cluster-precursors for structure formation of alkali zirconosilicates in the systems AOH-ZrO2-SiO2-H2O(A = Li-Cs):: algorithm for their identification and self-assembling modeling

被引：23

作者：

Ilyushin, GD ^{[1
]}

机构：

[1] RAS, Inst Crystallog, Moscow 119333, Russia

来源：

JOURNAL OF MATERIALS SCIENCE | 2006年 / 41卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

Polymer; Crystal Structure; Graph Theory; Structure Formation; Structural Unit;

D O I：

10.1007/s10853-006-4646-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The modeling of the crystal structure formation in hydrothermal systems AOH-ZrO2-SiO2-H2O (A - Li-Cs) was carried out on the base of combinatorial-topological analysis of the framework A,M-silicates structures. The mechanism of successive stages of the matrix assembly of the crystal structures from suprapolyhedral structural units (SSU invariants) was suggested. Modeling is based on the theory of space symmetry, graph theory and theory of hierarchic self-organization of the systems. (c) 2006 Springer Science + Business Media, Inc.

引用

页码：1563 / 1569

页数：7

共 10 条

[1]

HAWTHORNE FC, 1990, Z KRISTALLOGR, V192, P1

[2]

Ilyushin G. D., 2002, PHYS CRYSTALLIZATION, P82

[3] Crystal chemistry of zirconosilicates and their analogs: topological classification of MT frameworks and suprapolyhedral invariants [J].