Sinensiols H-J, three new lignan derivatives from Selaginella sinensis (Desv.) Spring

被引：0

作者：

Zhu, Qinfeng ^{[1
]}

Gao, Beibei ^{[2
]}

Chen, Qian ^{[1
]}

Luo, Tiantian ^{[1
]}

Xu, Guobo ^{[1
]}

Liao, Shanggao ^{[1
]}

机构：

[1] Guizhou Med Univ, Sch Pharm, 2 Dongqing Rd, Guiyang 550025, Peoples R China

[2] Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Chi, 132 Lanhei Rd, Kunming 650203, Peoples R China

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 18卷

关键词：

lignan derivatives; nitric oxide production inhibition; norlignans; Selaginella sinensis; SEX-PHEROMONE; GLUCOSIDE;

D O I：

10.3762/bjoc.18.146

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One new lignan sinensiol H (1) and two new bisnorlignans, sinensiols I and J (2 and 3), along with three known compounds were isolated from the whole plants of Selaginella sinensis. Their structures were elucidated on the basis of 1D and 2D NMR spectroscopy as well as high-resolution mass spectrometry. The absolute configuration of 1 was established by ECD calculation. Compounds 2 and 3 represent rare examples of naturally occurring 9,9'-bisnorlignans. All the isolated compounds were assayed for their inhibitory effects on LPS-induced nitric oxide production in RAW 264.7 macrophages.

引用

页码：1410 / 1415

页数：6

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