Lattice effects on the magnetic and transport properties in La1.4Sr1.6-xAxMn2O7 (A = Ca, Ba)

被引:22
作者
Chi, EO
Kwon, YU [1 ]
Kim, JT
Hur, NH
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Korea Res Inst Standards & Sci, Taejon 305600, South Korea
关键词
magnetically ordered materials; electronic transport; exchange and superexchange;
D O I
10.1016/S0038-1098(99)00101-5
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The structural and physical properties of the Ruddlesden-Popper phases La(1.4)Sr(1.6-x)A(x)Mn(2)O(7) (A = Ca, Ba) were studied. Single phase compounds were obtained up to x = 0.4 for Ca and x = 0.3 for Ba, respectively. Their magnetic and transport behavior is largely dependent upon the size of the A cations. By comparison with the magnetic and transport properties of the parent compound La1.4Sr1.6Mn2O7, the samples substituted by Ca and Ba exhibit reduced magnetic moments and conductivity. There is also a growing spin-glass like character with substitution. These can be explained by suppressed ferromagnetic double exchange interactions that result from local distortions by the size mismatch among La, Sr, and Ca/Ba. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:569 / 574
页数:6
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