The ternary bismuth-iron-antimony system: Experimental phase diagram study and thermodynamic evaluation

被引：31

作者：

Boa, D. ^{[2
]}

Hassam, S. ^{[1
]}

Krac, G. ^{[3
]}

Kotchi, K. P. ^{[2
]}

Rogez, J. ^{[1
]}

机构：

[1] Univ Paul Cezanne, Lab Thermodynam Proprietes Elect Contraintes Stru, UMR 6122, CNRS, Marseille 13397, France

[2] Univ Abobo Adjame, Lab Thermodynam & Phys Chim Milieu, UFR SFA, Abidjan, Cote Ivoire

[3] Univ Cocody, Lab Chim Mat Inorgan, UFR SSMT, Abidjan, Cote Ivoire

来源：

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2008年 / 32卷 / 02期

关键词：

phase diagrams; DTA; DSC; EPMA; optimization;

D O I：

10.1016/j.calphad.2008.01.001

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The ternary system Bi-Fe-Sb has been investigated using differential thermal analysis (DTA), differential scanning calorimetry (DSC) and electron probe microanalysis (EPMA). Two isoplethic sections were Studied: 80 at.% Bi and 30 at.% Sb. An isothermal section of the phase diagram was also studied at 523.15 K. Three invariant reactions were found: two ternary transitory peritectics and one ternary monotectic. No ternary compounds were found. In addition, a thermodynamic assessment was conducted. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：227 / 239

页数：13

共 52 条

[1] BEHAVIOR OF THE HEAT OF FORMATION IN THE BISMUTH ANTIMONY SYSTEM [J].

BADAWI, WA .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (07) :2599-2603

[2] Thermodynamic investigation of the moderately dilute liquid Bi-Fe-Sb alloys [J].

Boa, D ;

Hassam, S ;

Kotchi, KP ;

Rogez, J .

THERMOCHIMICA ACTA, 2006, 444 (01) :86-90

[3] The iron-antimony system:: enthalpies of formation of the FeSb2 and E-FeSb phases [J].

Boa, D ;

Hassam, S ;

Rogez, J ;

Kotchi, KP .

JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 365 (1-2) :228-232

[4]

Cook M, 1922, J I MET, V28, P421

[5] SGTE DATA FOR PURE ELEMENTS [J].

DINSDALE, AT .

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1991, 15 (04) :317-425

[6] SURVEY OF INTERFACE STABILITY-CRITERIA IN ELEMENTAL ALLOY SYSTEMS - GE-SI, BI-SB, AND SE-TE [J].

DISMUKES, JP ;

YIM, WM .

JOURNAL OF CRYSTAL GROWTH, 1974, 22 (04) :287-294

[7] THERMODYNAMIC PROPERTIES OF IRON + ANTIMONY [J].

DYNAN, J ;

MILLER, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1975, 7 (12) :1163-1172

[8] THE BINARY-SYSTEMS FE-SB, CO-SB AND NI-SB [J].

FESCHOTTE, P ;

LORIN, D .

JOURNAL OF THE LESS-COMMON METALS, 1989, 155 (02) :255-269

[9] THERMODYNAMIC EVALUATION OF THE SYSTEM BISMUTH-ANTIMONY [J].

FEUTELAIS, Y ;

MORGANT, G ;

DIDRY, JR .

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1992, 16 (02) :111-119

[10]

GAUTIER H, 1896, B SOC ENCOURAG IND N, P1293

← 1 2 3 4 5 6 →