The hydrated platinum(II) ion in aqueous solution-a combined theoretical and EXAFS spectroscopic study

被引：28
|
作者：
Hofer, Thomas S. [1 ]
Randolf, Bernhard R. [1 ]
Rode, Bernd M. [1 ]
Persson, Ingmar [2 ]
机构：
[1] Univ Innsbruck, Inst Gen Inorgan & Theoret Chem, Theoret Chem Div, A-6020 Innsbruck, Austria
[2] Swedish Univ Agr Sci, Dept Chem, SE-75007 Uppsala, Sweden
来源：
DALTON TRANSACTIONS | 2009年 / 09期
基金：
瑞典研究理事会; 美国国家卫生研究院;
关键词：
RAY-ABSORPTION SPECTROSCOPY; BODY DISTRIBUTION-FUNCTIONS; MOLECULAR CALCULATIONS; CONDENSED MATTER; WATER EXCHANGE; DIMETHYLSULFOXIDE; PALLADIUM(II); MECHANISM; DYNAMICS; KINETICS;
D O I：
10.1039/b819248k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrated platinum(II) ion, previously characterized as square-planar in aqueous solution, has been shown by quantum mechanical charge field molecular dynamic (QMCF MD) simulations and EXAFS experiments to be hexacoordinated with two additional ligands in elongated axial positions.
引用
收藏
页码：1512 / 1515
页数：4
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