The hydrated platinum(II) ion in aqueous solution-a combined theoretical and EXAFS spectroscopic study

被引：28
|
作者：
Hofer, Thomas S. [1 ]
Randolf, Bernhard R. [1 ]
Rode, Bernd M. [1 ]
Persson, Ingmar [2 ]
机构：
[1] Univ Innsbruck, Inst Gen Inorgan & Theoret Chem, Theoret Chem Div, A-6020 Innsbruck, Austria
[2] Swedish Univ Agr Sci, Dept Chem, SE-75007 Uppsala, Sweden
来源：
DALTON TRANSACTIONS | 2009年 / 09期
基金：
瑞典研究理事会; 美国国家卫生研究院;
关键词：
RAY-ABSORPTION SPECTROSCOPY; BODY DISTRIBUTION-FUNCTIONS; MOLECULAR CALCULATIONS; CONDENSED MATTER; WATER EXCHANGE; DIMETHYLSULFOXIDE; PALLADIUM(II); MECHANISM; DYNAMICS; KINETICS;
D O I：
10.1039/b819248k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrated platinum(II) ion, previously characterized as square-planar in aqueous solution, has been shown by quantum mechanical charge field molecular dynamic (QMCF MD) simulations and EXAFS experiments to be hexacoordinated with two additional ligands in elongated axial positions.
引用
收藏
页码：1512 / 1515
页数：4
相关论文
共 50 条
  • [21] Structures of polynuclear complexes of palladium(II) and platinum(II) formed by slow hydrolysis in acidic aqueous solution
    Torapava, Natallia
    Elding, Lars I.
    Maendar, Hugo
    Roosalu, Kaspar
    Persson, Ingmar
    DALTON TRANSACTIONS, 2013, 42 (21) : 7755 - 7760
  • [22] Adsorption of platinum ion from aged aqueous solution: application and comparative study between purified MWCNTs and triphenylphosphine MWCNTs
    Muleja, Adolph Anga
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2018, 25 (20) : 20032 - 20047
  • [23] Sorption of Cu (II) ion from aqueous solution by scrap tyre
    Oladoja, N. A.
    Ofomaja, A. E.
    Idiaghe, J. A.
    Akinlabi, A. K.
    Egbon, E. E.
    DESALINATION AND WATER TREATMENT, 2010, 16 (1-3) : 83 - 94
  • [24] Kinetic study of adsorption of copper (II) ion from aqueous solution using rice hull ash
    Wang, Li-Hua
    Lin, Chun-I
    Wu, Feng-Chin
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2010, 41 (05) : 599 - 605
  • [25] Study on Dynamics and Thermodynamics for Removal of Ph(II) from Aqueous Solution by Ion-Imprinted Sorbent
    Wang Limin
    Zhou Meihua
    PROGRESS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY, VOL II, PTS A AND B, 2009, : 1714 - 1719
  • [26] Study on the Interaction of Pentachlorophenol with Urease in Aqueous Solution by Multiple Spectroscopic Techniques
    Wang, Yan-Qing
    Zhang, Gen-Cheng
    Zhang, Hong-Mei
    JOURNAL OF SOLUTION CHEMISTRY, 2011, 40 (03) : 458 - 469
  • [27] Mechanistic aspects of the ligand substitution reaction of diaquaethylenediamine-platinum(II) ion with 2-thiouracil in aqueous medium
    Nandi, Debabrata
    Ray, Sumon
    Laskar, Subrata
    Ghosh, Alak Kumar
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2013, 90 (07) : 913 - 921
  • [28] Tautomeric transformations of piroxicam in solution: a combined experimental and theoretical study
    Ivanova, D.
    Deneva, V.
    Nedeltcheva, D.
    Kamounah, F. S.
    Gergov, G.
    Hansen, P. E.
    Kawauchi, S.
    Antonov, L.
    RSC ADVANCES, 2015, 5 (40) : 31852 - 31860
  • [29] A Combined Theoretical and Experimental Approach for Platinum Catalyzed 1,2-Propanediol Aqueous Phase Reforming
    Schimmenti, Roberto
    Cortese, Remedios
    Godina, Lidia
    Prestianni, Antonio
    Ferrante, Francesco
    Duca, Dario
    Murzin, Dmitry Yu.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (27) : 14636 - 14648
  • [30] Combined Experimental and Theoretical Study on the Reactivity of Compounds I and II in Horseradish Peroxidase Biomimetics
    Ji, Li
    Franke, Alicja
    Brindell, Malgorzata
    Oszajca, Maria
    Zahl, Achim
    van Eldik, Rudi
    CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (44) : 14437 - 14450
12345