Microwave Assisted Synthesis of meso-Tetraphenylporphyrin and Its Application for Trace Metal Spectrophotometric Determination

被引:0
作者
Givianrad, M. H. [1 ]
Bahrami, A. [1 ]
机构
[1] Islamic Azad Univ, Sci & Res Branch, Dept Chem, Tehran, Iran
关键词
Microwave; Meso-tetraphenylporphyrin; Zinc; UV-visible spectroscopy; PORPHYRINS;
D O I
10.14233/ajchem.2013.14273
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of meso-tetraphenylporphyrin with quantitative yield in presence of p-toluene sulfonic acid as new catalyst under microwave irradiation was accomplished. The meso-tetraphenylporphyrin was characterized by means of elemental analysis, UV-visible spectra, H-1 NMR spectra, infrared spectra and was used as chelating agent for direct determination of zinc ions by UV-visible spectroscopy.
引用
收藏
页码:6102 / 6104
页数:3
相关论文
共 15 条
[1]   Investigation of atropisomerism in ortho-substituted tetraphenylporphyrins: An experimental module involving synthesis, chromatography, and NMR spectroscopy [J].
Beeston, RF ;
Stitzel, SE ;
Rhea, MA .
JOURNAL OF CHEMICAL EDUCATION, 1997, 74 (12) :1468-1471
[2]   Porphyrins in analytical chemistry. A review [J].
Biesaga, M ;
Pyrzynska, K ;
Trojanowicz, M .
TALANTA, 2000, 51 (02) :209-224
[3]   SYNTHESIS AND FILM-FORMING PROPERTIES OF METAL-COMPLEXES OF OCTADECYL ETHERS OF 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)PORPHYRIN [J].
BONNETT, R ;
IOANNOU, S ;
JAMES, AG ;
PITT, CW ;
SOE, MMZ .
JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (08) :793-799
[4]   Microwave-assisted synthesis of metalloporphyrazines [J].
Chandrasekharam, M. ;
Rao, Ch. Srinivasa ;
Singha, Surya P. ;
Kantam, M. Lakshmi ;
Reddy, M. Ramesh ;
Reddy, P. Yella ;
Toru, T. .
TETRAHEDRON LETTERS, 2007, 48 (14) :2627-2630
[5]   Microwave assisted synthesis of novel annealed porphyrins [J].
Elghamry, Ibrahim ;
Tietze, Lutz F. .
TETRAHEDRON LETTERS, 2008, 49 (25) :3972-3975
[6]  
Falk JE, 1975, PORPHYRINS METALLOPO
[7]  
Fischer H., 1940, CHEM PYRROLS, V2, P48
[8]   Systems of acids, bases and salts [J].
Franklin, EC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1924, 46 :2137-2151
[9]  
Lemberg R., 1949, HAEMATIN COMPOUNDSAN
[10]   Microwave-assisted synthesis and reverse saturable absorption of phthalocyanines and porphyrins [J].
Liu, MO ;
Tai, CH ;
Wang, WY ;
Chen, JR ;
Hu, AT ;
Wei, TH .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (06) :1078-1084