Fused-Ring Bulky "Rind" Groups Producing New Possibilities in Elemento-Organic Chemistry

被引：43

作者：

Matsuo, Tsukasa ^{[1
,3
]}

Tamao, Kohei ^{[2
]}

机构：

[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan

[2] RIKEN, Wako, Saitama 3510198, Japan

[3] PRESTO, JST, Kawaguchi, Saitama 3320012, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2015年 / 88卷 / 09期

关键词：

TRANSITION-METAL-COMPLEXES; S-HYDRINDACENE SKELETON; JAHN-TELLER DISTORTION; HIGH-SPIN IRON(II); AR-ASTERISK-OH; ROOM-TEMPERATURE; DIBORANE(4) COMPOUND; CONJUGATED MATERIALS; BOND FORMATION; HEAVY KETONES;

D O I：

10.1246/bcsj.20150130

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic stabilization with sterically bulky substituents or ligands has played a pivotal role in exploring a large variety of unsaturated compounds or low-coordinated complexes. This article describes our findings that a series of fused-ring octa-R-substituted s-hydrindacenyl groups (Rind groups), which we developed since 2007, can act as unique protecting groups both in main group chemistry and in transition-metal chemistry. The synthesis, structures, and properties of various types of highly reactive unsaturated and low-coordinated element-organic compounds of Groups 1, 2, 8, 11, and 13-17 featuring the bulky Rind groups are covered.

引用

页码：1201 / 1220

页数：20

共 111 条

[51]

Li LC, 2012, NAT CHEM, V4, P361, DOI [10.1038/nchem.1305, 10.1038/NCHEM.1305]

[52] SMALL RINGS .25. TETRA-TERT-BUTYLTETRAHEDRANE [J].

MAIER, G ;

PFRIEM, S ;

SCHAFER, U ;

MATUSCH, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (07) :520-521

[53] TETRAHEDRANE AND CYCLOBUTADIENE [J].

MAIER, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03) :309-333

[54] The first kinetically stabilized germanethiones and germaneselones: Syntheses, structures, and reactivities [J].

Matsumoto, T ;

Tokitoh, N ;

Okazaki, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (38) :8811-8824

[55] Synthesis and Structures of a Series of Bulky "Rind-Br" Based on a Rigid Fused-Ring s-Hydrindacene Skeleton [J].

Matsuo, Tsukasa ;

Suzuki, Katsunori ;

Fukawa, Tomohide ;

Li, Baolin ;

Ito, Mikinao ;

Shoji, Yoshiaki ;

Otani, Takashi ;

Li, Liangchun ;

Kobayashi, Megumi ;

Hachiya, Makoto ;

Tahara, Yoshiyuki ;

Hashizume, Daisuke ;

Fukunaga, Takeo ;

Fukazawa, Aiko ;

Li, Yongming ;

Tsuji, Hayato ;

Tamao, Kohei .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2011, 84 (11) :1178-1191

[56] π-conjugated phosphasilenes stabilized by fused-ring bulky "Rind" groups [J].

Matsuo, Tsukasa ;

Li, Baolin ;

Tamao, Kohei .

COMPTES RENDUS CHIMIE, 2010, 13 (8-9) :1104-1110

[57] π-Conjugated disilenes stabilized by fused-ring bulky "Rind" groups [J].

Matsuo, Tsukasa ;

Kobayashi, Megumi ;

Tamao, Kohei .

DALTON TRANSACTIONS, 2010, 39 (39) :9203-9208

[58] Direct Spectroscopic Observation of Large Quenching of First-Order Orbital Angular Momentum with Bending in Monomeric, Two-Coordinate Fe(II) Primary Amido Complexes and the Profound Magnetic Effects of the Absence of Jahn- and Renner-Teller Distortions in Rigorously Linear Coordination [J].

Merrill, W. Alexander ;

Stich, Troy A. ;

Brynda, Marcin ;

Yeagle, Gregory J. ;

Fettinger, James C. ;

De Hont, Raymond ;

Reiff, William M. ;

Schulz, Charles E. ;

Britt, R. David ;

Power, Philip P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (35) :12693-12702

[59] BIRADICALS AND BIRADICALOIDS - A UNIFIED VIEW [J].

MICHL, J ;

BONACICKOUTECKY, V .

TETRAHEDRON, 1988, 44 (24) :7559-7585

[60] An extremely active catalyst for the Negishi cross-coupling reaction [J].

Milne, JE ;

Buchwald, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (40) :13028-13032

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