Polyurethanes from Isosorbide-Based Diisocyanates

被引：73
作者：
Zenner, Michael D. [1 ]
Xia, Ying [2 ]
Chen, Jason S. [1 ]
Kessler, Michael R. [2 ]
机构：
[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
[2] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA
来源：
CHEMSUSCHEM | 2013年 / 6卷 / 07期
基金：
美国国家科学基金会;
关键词：
green chemistry; isocyanates; polymers; rearrangement; renewable resources; POLYMERIZATION; DIAMINES; RUTHENIUM; ALCOHOLS; DIOLS;
D O I：
10.1002/cssc.201300126
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Benign building blocks: Stereochemically pure diisocyanates were prepared on a multigram scale from succinic anhydride and isosorbide or isomannide. Characterization of polyurethanes that were produced from these diisocyanates revealed low polydispersity, high thermal stability, and stereochemistry- dependent morphology. If biobased succinic anhydride is used, then no stoichiometric petroleum-derived reagents are required in the synthesis of these materials. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1182 / 1185
页数：4
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