Synthesis, Crystal Structure and Properties of 1D Ribbon-Like Complex [Co(DMPhTPY)V2O6]n with Substituted Terpyridine and Polyoxovanadate Ligand

被引：0

作者：

Yang Hao ^{[1
]}

Chen Jian-Guo ^{[1
]}

Feng Yu-Quan ^{[1
]}

Bao Xiao-Yu ^{[1
]}

Sun Ru-Zhong ^{[1
]}

机构：

[1] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Henan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 07期

关键词：

hydrothermal synthesis; coordination polymer; crystal structure; thermal stability; luminescence property; magnetic property; HYDROTHERMAL SYNTHESES; LITHIUM BATTERIES; VANADIUM-OXIDE; CHAINS; 2''-TERPYRIDINE; COPPER(II); COBALT(II); OXYGEN; METAL;

D O I：

10.3969/j.issn.1001-4861.2013.00.203

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 1D ribbon-like structure coordination polymer of [Co(DMPhTPY)V2O6](n) (DMPhTPY=6,6 ''-dimethyl-4' -phenyl-2,2':6',2 ''-terpyridine)was synthesized under the hydrothermal condition. The structure was characterized by elemental analysis, IR and X-ray single crystal diffraction. The crystal structure of the complex belongs to triclinic system, space group Pi. Thermal stability, photoluminescence property and magnetic susceptibility of the complex have been investigated. The results show that the title complex has high thermal stability and antiferromagnetic exchange interaction between the Co(II) ions. CCDC: 880007.

引用

页码：1454 / 1458

页数：5

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