Effects of phosphorus addition on the properties of Sn-9Zn lead-free solder alloy

被引:15
作者
Huang, Hui-zhen [1 ]
Wei, Xiu-qin [1 ]
Tan, Dun-qiang [1 ]
Zhou, Lang [1 ]
机构
[1] Nanchang Univ, Sch Mat Sci & Engn, Nanchang 330031, Peoples R China
基金
中国国家自然科学基金;
关键词
lead-free solder; phosphorus; wettability; oxidation; corrosion; CU SUBSTRATE; ZN; MICROSTRUCTURE; AG;
D O I
10.1007/s12613-013-0766-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This article explores the effects of phosphorus addition on the wettability between Sn-9Zn solder alloy and Cu substrates, the oxidation behavior and the corrosion behavior of Sn-9Zn solder alloy. Spreading test was used to characterize the wettability of Sn-9Zn-xP solder alloys to Cu substrates. The oxidation and corrosion behaviors of Sn-9Zn-xP solder alloys were determined by means of weight gaining, and secondary ion mass spectrometry was used to analyze the oxygen content. The role and mechanism of P in the solder alloys were also discussed. It is found that the addition of P can significantly improve the wettability of the solder alloys. Incorporating P into Sn-9Zn solder alloy obviously decreases the oxygen content and enhances the oxidation and corrosion resistance. Microstructure observations show that an appropriate amount of P can greatly refine coarse rod-like Zn-rich phases in Sn-9Zn solder alloy.
引用
收藏
页码:563 / 567
页数:5
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