Facile, alternative route to lubeluzole, its enantiomer, and the racemate

被引:29
作者
Bruno, C [1 ]
Carocci, A [1 ]
Catalano, A [1 ]
Cavalluzzi, MM [1 ]
Corbo, F [1 ]
Franchini, C [1 ]
Lentini, G [1 ]
Tortorella, V [1 ]
机构
[1] Univ Bari, Fac Farm, Dipartimento Farmacochim, I-70126 Bari, Italy
关键词
stroke; sodium channel; stereospecific synthesis; enantiomers; enantiomeric excess;
D O I
10.1002/chir.20240
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
Lubeluzole [(S)-9] has been synthesized by a convergent synthesis, alkylation of N-methyl-N-piperidin-4-yl-1,3-benzothiazol-2-amine (4) with (+)-(R)-1-chloro-3-(3,4-difluorophenoxy)propan-2-ol [(+)-(R)-8] being the key step. Alcohol (+)-(R)-8 was obtained from commercially available (R)-epichlorohydrin [(R)-6], while the thiazole derivative 4 was easily obtained starting from N-protected piperidin-4-one (1) in a three-step procedure. The same method was used in order to obtain both the (R)-stereoisomer of lubeluzole [(R)-9] and its racemate [(RS)-9]. Overall yields ranged from 20% to 35%. The enantiomeric excess values for (S)-9 and (R)-9 were 97% and 94% respectively, as analyzed by chiral HPLC.
引用
收藏
页码:227 / 231
页数:5
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