One-step fabrication of N-doped TiO2 inverse opal films with visible light photocatalytic activity

被引:23
作者
Hu, Zhiyan [1 ]
Xu, Lianbin [1 ]
Wang, Lingling [1 ]
Huang, Yan [1 ]
Xu, Limin [1 ]
Chen, Jianfeng [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Visible light; N doping; Inverse opal; TiO2; film; TITANIUM-OXIDE; ARRAYS;
D O I
10.1016/j.catcom.2013.06.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
N-doped TiO2 inverse opal films were fabricated by a novel method through one-step coassembly of polymer colloidal spheres and titania precursor. This coassembly approach removed the need of preassembled colloidal crystal for precursor solution infiltration and respective chemicals for titania formation and nitrogen doping. Less crack films with well ordered inverse opal structure could be produced by adding appropriate amount of TiBALDH (titanium(IV)-bis-lactato-bis-ammonium dihydroxide) into the precursor solution. The films prepared at the optimized condition showed enhanced visible light photocatalytic activity, which could be attributed to both the N doping effect and their unique inverse opal structure. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:106 / 110
页数:5
相关论文
共 18 条
[1]   Enhanced nitrogen doping in TiO2 nanoparticles [J].
Burda, C ;
Lou, YB ;
Chen, XB ;
Samia, ACS ;
Stout, J ;
Gole, JL .
NANO LETTERS, 2003, 3 (08) :1049-1051
[2]   Synergy of slow photon and chemically amplified photochemistry in platinum nanocluster-loaded inverse titania opals [J].
Chen, Jennifer I. L. ;
Loso, Edward ;
Ebrahim, Naazia ;
Ozin, Geoffrey A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (16) :5420-+
[3]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[4]   TiO2 photocatalysis:: A historical overview and future prospects [J].
Hashimoto, K ;
Irie, H ;
Fujishima, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (12) :8269-8285
[5]   Assembly of large-area, highly ordered, crack-free inverse opal films [J].
Hatton, Benjamin ;
Mishchenko, Lidiya ;
Davis, Stan ;
Sandhage, Kenneth H. ;
Aizenberg, Joanna .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2010, 107 (23) :10354-10359
[6]   Enhancing Visible Light Photo-oxidation of Water with TiO2 Nanowire Arrays via Cotreatment with H2 and NH3: Synergistic Effects between Ti3+ and N [J].
Hoang, Son ;
Berglund, Sean P. ;
Hahn, Nathan T. ;
Bard, Allen J. ;
Mullins, C. Buddie .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (08) :3659-3662
[7]   Synthesis of macroporous minerals with highly ordered three-dimensional arrays of spheroidal voids [J].
Holland, BT ;
Blanford, CF ;
Stein, A .
SCIENCE, 1998, 281 (5376) :538-540
[8]   Synthesis of highly ordered, three-dimensional, macroporous structures of amorphous or crystalline inorganic oxides, phosphates, and hybrid composites [J].
Holland, BT ;
Blanford, CF ;
Do, T ;
Stein, A .
CHEMISTRY OF MATERIALS, 1999, 11 (03) :795-805
[9]   Visible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping [J].
Ihara, T ;
Miyoshi, M ;
Iriyama, Y ;
Matsumoto, O ;
Sugihara, S .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 42 (04) :403-409
[10]   Single-crystal colloidal multilayers of controlled thickness [J].
Jiang, P ;
Bertone, JF ;
Hwang, KS ;
Colvin, VL .
CHEMISTRY OF MATERIALS, 1999, 11 (08) :2132-2140