Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction

被引：34

作者：

Day, Benjamin M. ^{[2
]}

Knowelden, William ^{[2
]}

Coles, Martyn P. ^{[1
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand

[2] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 36期

关键词：

AMIDINATE COMPLEXES; CRYSTAL; KETONES; DONOR;

D O I：

10.1039/c2dt31442h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Magnesium-aryloxide and -amide compounds supported by amidinate ligands are accessible in two-steps from a suitable Grignard reagent. Both species are active for the dimerization of benzaldehyde. The slower initiation by the aryloxide was exploited in the isolation of a bis-mesitylaldehyde adduct.

引用

页码：10930 / 10933

页数：4