Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction

被引：34

作者：

Day, Benjamin M. ^{[2
]}

Knowelden, William ^{[2
]}

Coles, Martyn P. ^{[1
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand

[2] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 36期

关键词：

AMIDINATE COMPLEXES; CRYSTAL; KETONES; DONOR;

D O I：

10.1039/c2dt31442h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Magnesium-aryloxide and -amide compounds supported by amidinate ligands are accessible in two-steps from a suitable Grignard reagent. Both species are active for the dimerization of benzaldehyde. The slower initiation by the aryloxide was exploited in the isolation of a bis-mesitylaldehyde adduct.

引用

页码：10930 / 10933

页数：4

共 31 条

[21] Microwave-assisted efficient thiolate-catalysed homo- and crossed intermolecular Tishchenko reactions [J].

O' Connor, Cornelius J. ;

Manoni, Francesco ;

Curran, Simon P. ;

Connon, Stephen J. .

NEW JOURNAL OF CHEMISTRY, 2011, 35 (03) :551-553

[22] Preparation and properties of RMg(macrocycle)+ cations with accompanying anions derived from acidic hydrocarbons or a hindered phenol [J].

Pajerski, AD ;

Squiller, EP ;

Parvez, M ;

Whittle, RR ;

Richey, HG .

ORGANOMETALLICS, 2005, 24 (05) :809-814

[23] Monomeric and dimeric amidinate complexes of magnesium [J].

Sadique, AR ;

Heeg, MJ ;

Winter, CH .

INORGANIC CHEMISTRY, 2001, 40 (25) :6349-6355

[24] Synthesis and characterization of a series of sterically-hindered amidines and their lithium and magnesium complexes [J].

Schmidt, JAR ;

Arnold, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (14) :2890-2899

[25] The Tishchenko reaction: A classic and practical tool for ester synthesis [J].

Seki, Tsunetake ;

Nakajo, Tetsuo ;

Onaka, Makoto .

CHEMISTRY LETTERS, 2006, 35 (08) :824-829

[26] Synthesis, characterization and crystal structures of isothiocyanate and carbodiimide complexes derived from organomagnesium reagents: Insertion into Mg-X (X=C or N) bonds [J].

Srinivas, B ;

Chang, CC ;

Chen, CH ;

Chiang, MY ;

Chen, IT ;

Wang, Y ;

Lee, GH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (06) :957-963

[27] Amino alcohol effects on the ruthenium(II)-catalysed asymmetric transfer hydrogenation of ketones in propan-2-ol [J].

Takehara, J ;

Hashiguchi, S ;

Fujii, A ;

Inoue, S ;

Ikariya, T ;

Noyori, R .

CHEMICAL COMMUNICATIONS, 1996, (02) :233-234

[28]

Tischenko W., 1906, Chem. Zentralbl, V77, P1309

[29] Complexes of the bis(trimethylsilyl)-benzamidinato ligand 'siam':: synthesis and X-ray structures of (siam)2M, (siam)(siamH)MX (M = Ni, Pd), (siam)2MnI and (siam)ReO3, and their reactivity towards CO2 [J].

Walther, D ;

Gebhardt, P ;

Fischer, R ;

Kreher, U ;

Gorls, H .

INORGANICA CHIMICA ACTA, 1998, 281 (02) :181-189

[30] SYNTHESIS OF MAGNESIUM BIS[N,N'-BIS(TRIMETHYLSILYL)BENZAMIDINATE] AS BOTH BIS(THF) AND BENZONITRILE ADDUCT [J].

WESTERHAUSEN, M ;

HAUSEN, HD .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 615 (09) :27-34

← 1 2 3 4 →