Amino-containing cross-linked ionic copolymer-anchored heteropoly acid for solvent-free oxidation of benzyl alcohol with H2O2

被引：38

作者：

Leng, Yan ^{[1
]}

Wang, Jun ^{[2
]}

Jiang, Pingping ^{[1
]}

机构：

[1] Jiangnan Univ, Minist Educ, Sch Chem & Mat Engn, Key Lab Food Colloids & Biotechnol, Wuxi 214122, Peoples R China

[2] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2012年 / 27卷

基金：

中国国家自然科学基金;

关键词：

Heteropoly acid; Oxidation of alcohol; Ionic liquid; Cross-linked polymer; Heterogeneous catalysis; SELECTIVE OXIDATION; LIQUID; POLYOXOMETALATE; CATALYST; ALDEHYDES; HYBRID; SALTS;

D O I：

10.1016/j.catcom.2012.07.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Amino-containing cross-linked ionic copolymer-anchored HPA catalysts were prepared by the anion-exchange of polydivinylbenzene/amino-functionalized ionic liquids copolymers with Keggin heteropoly acid (HPA), and were characterized by H-1 NMR, FT-IR, TG, XRD, SEM, TEM, BET surface area, and elemental analysis. Their catalytic performance for oxidation of benzyl alcohol with H2O2 was studied under solvent-free conditions. The results demonstrated that the catalysts were very active and selective, and could be reused after simple separation. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：101 / 104

页数：4

共 50 条

[1] A novel heteropolyanion-based amino-containing cross-linked ionic copolymer catalyst for epoxidation of alkenes with H2O2
Leng, Yan
Zhang, Weijie
Wang, Jun
Jiang, Pingping
APPLIED CATALYSIS A-GENERAL, 2012, 445 : 306 - 311
[2] Amino functionalized bipyridine-heteropolyacid ionic hybrid: A recyclable catalyst for solvent-free oxidation of benzyl alcohol with H2O2
Leng, Yan
Zhao, Pingping
Zhang, Mingjue
Wang, Jun
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 358 : 67 - 72
[3] Solvent-free oxidation of toluene in an ionic liquid with H2O2 as oxidant
Lu, Bin
Cai, Na
Sun, Jia
Wang, Xin
Li, Xin
Zhao, Jingxiang
Cai, Qinghai
CHEMICAL ENGINEERING JOURNAL, 2013, 225 : 266 - 270
[4] Iron-chloride ionic liquid immobilized on SBA-15 for solvent-free oxidation of benzyl alcohol to benzaldehyde with H2O2
Cang, Ruibai
Lu, Bin
Li, Xiaopeng
Niu, Rui
Zhao, Jingxiang
Cai, Qinghai
CHEMICAL ENGINEERING SCIENCE, 2015, 137 : 268 - 275
[5] Ni2+-containing ionic liquid immobilized on silica: Effective catalyst for styrene oxidation with H2O2 at solvent-free condition
Liu, Gang
Hou, Minqiang
Song, Jiyuan
Zhang, Zhaofu
Wu, Tainbin
Han, Buxing
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 316 (1-2) : 90 - 94
[6] Molybdovanadophosphoric anion ionic liquid as a reusable catalyst for solvent-free benzene oxidation to phenol by H2O2
Yuan, Chengyuan
Gao, Xionghou
Pan, Zhishuang
Li, Xueli
Tan, Zhengguo
CATALYSIS COMMUNICATIONS, 2015, 58 : 215 - 218
[7] Fe-Cu-chloride ionic liquid immobilized SBA-15 for solvent-free oxidation of styrene to benzaldehyde with H2O2
Yan, Yuwei
Li, Hongyan
Li, Songnan
Zhang, Jiawei
Zhao, Jingxiang
Cai, Qinghai
NEW JOURNAL OF CHEMISTRY, 2024, 48 (26) : 11776 - 11782
[8] Mesoporous Polyoxometalate-Based Ionic Hybrid As a Triphasic Catalyst for Oxidation of Benzyl Alcohol with H2O2 on Water
Chen, Guojian
Zhou, Yu
Long, Zhouyang
Wang, Xiaochen
Li, Jing
Wang, Jun
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (06) : 4438 - 4446
[9] Heteropoly ionic liquids functionalized γ-Fe2O3 NPs: synthesis, characterization, and catalytic application in selective oxidation of benzyl alcohol to benzaldehyde using H2O2 as a green oxidant
Abdulaziz Abdullah Qasem Ali
Zeba N. Siddiqui
Research on Chemical Intermediates, 2023, 49 : 1085 - 1113
[10] Heteropoly ionic liquids functionalized ?-Fe2O3 NPs: synthesis, characterization, and catalytic application in selective oxidation of benzyl alcohol to benzaldehyde using H2O2 as a green oxidant
Ali, Abdulaziz Abdullah Qasem
Siddiqui, Zeba N.
RESEARCH ON CHEMICAL INTERMEDIATES, 2023, 49 (03) : 1085 - 1113

← 1 2 3 4 5 →