ClO4 -- directed Assembly of Two CoII Complexes Based on Flexible N-donor Ligands: Syntheses, Crystal Structures and Magnetic Properties

被引：0

作者：

Wen Guo-Xuan ^{[1
,2
]}

Dong Wen-Wen ^{[1
]}

Pan Li-Qing ^{[2
]}

Li Dong-Sheng ^{[1
]}

机构：

[1] China Three Gorges Univ, Coll Mat & Chem Engn, Hubei Prov Collaborat Innovat Ctr New Energy Micr, Yichang 443002, Peoples R China

[2] China Three Gorges Univ, Coll Sci, Yichang 443002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Co-II complex; interpenetrating network; crystal structure; magnetic properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; MOF; NETWORKS; TOPOLOGY; NETS;

D O I：

10.14102/j.cnki.0254-5861.2011-1266

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Co-II ions with 1,4-bis(imidazol)butane (bimb) or 1,4-bis(triazol)bu-tane (bitb) in the presence of ClO4-, respectively affords two CoII coordination complexes, namely {[Co (bimb)(3)]center dot 2ClO(4)}(n) (I) and {[Co (bitb)(3)]center dot 2ClO(4)}(n) (II). Single-crystal X-ray analysis indicates that both complexes I and II show the same alpha-Po topological structures. However, complex I exhibits a 2-fold interpenetrating network, while complex II features a 3-fold interpenetrating network. In addition, solid-state properties such as thermal stabilities and magnetic properties of two complexes were also investigated.

引用

页码：89 / 98

页数：10